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JEE Main 202310 AprilMorning Shift
Exam
JEE Main
Year
2023
Date
10 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Thermodynamics (C)

JEE Main 2023 · 10 April · Morning Shift · Chemistry · Thermodynamics (C)

Given (A) 2CO(g) + O _ 2 (g) → 2 CO _ 2 (g) Δ H _ 1 ^ o = - xkJ mol...

Given

(A) 2CO(g)+O2(g)→2CO2(g)ΔH1o=−xkJmol−12CO\left(g\right) + {O}_{2}\left(g\right) \to 2{CO}_{2}\left(g\right){\Delta H}_{1}^{o} = - xkJ{mol}^{- 1}

(B) C(graphite)+O2(g)→CO2(g)ΔH2o=−ykJmol−1C\left(graphite\right) + {O}_{2}\left(g\right) \to {CO}_{2}\left(g\right){\Delta H}_{2}^{o} = - ykJ{mol}^{- 1}

The ∆Ho∆ {H}^{o} for the reaction C(graphite)+12O2(g)→CO(g)C\left(graphite\right) + \dfrac{1}{2}{O}_{2}\left(g\right) \to CO\left(g\right) is

Options

  1. A2x−y2\dfrac{2x - y}{2}
  2. Bx+2y2\dfrac{x + 2y}{2}
  3. Cx−2y2\dfrac{x - 2y}{2}
  4. D2y−x2y - x

Correct answer

C. x−2y2\dfrac{x - 2y}{2}

Step-by-step solution

(A) 2CO(g)+O2(g)→2CO2(g)ΔH1o=−xkJmol−12CO\left(g\right) + {O}_{2}\left(g\right) \to 2{CO}_{2}\left(g\right){\Delta H}_{1}^{o} = - xkJ{mol}^{- 1}

(B) Cgraphite+O2(g)→CO2(g)ΔH2o=−ykJmol−1{C}_{graphite} + {O}_{2}\left(g\right) \to {CO}_{2}\left(g\right){\Delta H}_{2}^{o} = - ykJ{mol}^{- 1}

If the equation is multiplied the value nn, then the enthalpy change value also multiplied by factor n.n . If the enthalpy is positive in one direction, it is negative in other direction.

Multiply equation BB by 22 and subtract equation (A)\left(A\right) from it

2Cgraphite+O2(g)→2CO(g)ΔH∘=x−2y2{C}_{graphite} + {O}_{2}\left(g\right) \to 2CO\left(g\right){\Delta H}^{∘} = x - 2y

Cgraphite+12O2→CO;ΔH∘=x−2y2{C}_{graphite} + \dfrac{1}{2}{O}_{2} \to CO; {\Delta H}^{∘} = \dfrac{x - 2y}{2}

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