The incorrect statements from the following is: A. The electrical...

${E}_{cell}^{∘}$ is dependent on the equilibrium constant, $K$, which is not dependent on the pressure of any gas involved in the cell. Relation between Electrochemical Cell Potential and Gibbs free Energy change is given by; $\DeltaG = - nFE$ where Delta G is Gibbs Free energy change , n is the number of electrons involved in the reaction and F is Faraday and E is the Cell potential.

We know that,

$dG = VdP - SdT$

At constant pressure $dP = 0$

$⇒ dG = - SdT$

$S = - \dfrac{dG}{dT} ∆ S = - {\left(\dfrac{∆ \left(dG\right)}{dT}\right)}_{P}$

$⇒ {dE}_{cell}^{°}dT = \dfrac{∆ S}{nF}$

A cell is operating reversibly if the cell potential is exactly balanced by an opposing source of potential difference.