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JEE Main 202228 JulyEvening Shift
Exam
JEE Main
Year
2022
Date
28 July
Shift
Evening Shift
Subject
Chemistry
Chapter
Thermodynamics (C)

JEE Main 2022 · 28 July · Evening Shift · Chemistry · Thermodynamics (C)

Given below are two statements: One is labelled as Assertion A and...

Given below are two statements: One is labelled as Assertion AA and the other is labelled as Reason RR

Assertion AA : The reduction of a metal oxide is easier if the metal formed is in liquid state than solid state.

Reason RR : The value of ΔGΘ{\Delta G}^{Θ} becomes more on negative side as entropy is higher in liquid state than solid state.

In the light of the above statements. Choose the most appropriate answer from the options given below

Options

  1. ABoth AA and RR are correct and RR is the correct explanation of AA
  2. BBoth AA and RR are correct but RR is NOT the correct explanation of AA
  3. CAA is correct but RR is not correct
  4. DAA is not correct but RR is correct

Correct answer

A. Both AA and RR are correct and RR is the correct explanation of AA

Step-by-step solution

The entropy is higher if the metal is in liquid state than when it is in solid state. The value of entropy change (∆S)( ∆ S ) of the reduction process is more on positive side when the metal formed is in liquid state and the metal oxide being reduced is in solid state. Thus the value of ∆fG{∆}_{f}G becomes more on negative side and the reduction becomes easier.

ΔG=ΔH−TΔS\Delta G = \Delta H - T \Delta S

∵∵ Entropy of liquid is more than solid

∴∴ on melting the entropy increases and ΔG\Delta G becomes more negative and hence it becomes easier to reduce metal.

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