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JIPMER 2016
Exam
JIPMER
Year
2016
Subject
Chemistry
Chapter
Coordination Compounds

JIPMER 2016 · Chemistry · Coordination Compounds

In [CO(H_2 O)_6]^ 2+ , there are three unpaired electrons present....

In [CO(H2O)6]2+\left[\mathrm{CO}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}, there are three unpaired electrons present. The μcalculated \mu_{\text{calculated }} is 3.87 BM which is quite different from the μexperimental \mu_{\text{experimental }} of 4.40 BM . This is because ofIn [CO(H_2 O)_6]^ 2+ , there are three unpaired electrons present. The μ_ calculated is 3.87 BM which is quite

Options

  1. Aincrease in number of unpaired electrons
  2. Bsome contribution of the orbital motion of the electron to the magnetic moment
  3. Cchange in orbital spin of the electron
  4. Dd-d transition

Correct answer

B. some contribution of the orbital motion of the electron to the magnetic moment

Step-by-step solution

In [Co(H2O)6]2+\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}, there are three unpaired electrons present as, In [CO(H_2 O)_6]^ 2+ , there are three unpaired electrons present. The μ_ calculated is 3.87 BM which is quite μcal=n(n+1)BM=3(3+1)BM=3.87BM\mu_{\mathrm{cal}}=\sqrt{n(n+1)} \mathrm{BM}=\sqrt{3(3+1)} \mathrm{BM}=3.87 \mathrm{BM} As, the t2gt_{2 g} orbital is unsymmetrically filled hence due to orbital motion contribution, magnetic moment goes with the value 4.40 BM
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