JIPMER 2016
- Exam
- JIPMER
- Year
- 2016
- Subject
- Chemistry
- Chapter
- Coordination Compounds
JIPMER 2016 · Chemistry · Coordination Compounds
In [CO(H_2 O)_6]^ 2+ , there are three unpaired electrons present....
In , there are three unpaired electrons present. The is 3.87 BM which is quite different from the of 4.40 BM .
This is because of![In [CO(H_2 O)_6]^ 2+ , there are three unpaired electrons present. The μ_ calculated is 3.87 BM which is quite](/api/proxy-image?clean=1&b=aHR0cHM6Ly9jZG4tcXVlc3Rpb24tcG9vbC5nZXRtYXJrcy5hcHAvcHlxL2ppcG1lci9iRGEwNllZWFZJZ2o3MHp0bHh2dll6eklqSEMyQUtaTG4tNGFUSUE0NDlnLm9yaWdpbmFsLmZ1bGxzaXplLnBuZw)
Options
- Aincrease in number of unpaired electrons
- Bsome contribution of the orbital motion of the electron to the magnetic moment
- Cchange in orbital spin of the electron
- Dd-d transition
Correct answer
B. some contribution of the orbital motion of the electron to the magnetic moment
Step-by-step solution
In , there are three unpaired electrons present as,
As, the orbital is unsymmetrically filled hence due to orbital motion contribution, magnetic moment goes with the value 4.40 BM