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AIIMS 2001
Exam
AIIMS
Year
2001
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

AIIMS 2001 · Chemistry · Chemical Bonding and Molecular Structure

Hybridisation in CH_3, + C H_3 and C _3 are respectively

Hybridisation in CH3,C+H3\mathrm{CH}_3, \stackrel{+}{\mathrm{C}} \mathrm{H}_3 and C‾3\overline{\mathrm{C}}_3 are respectively

Options

  1. Asp2,sp2,sp3s p^2, s p^2, s p^3
  2. Bsp2,sp3,sp3s p^2, s p^3, s p^3
  3. Csp3,sp3,sp2s p^3, s p^3, s p^2
  4. Dsp3,sp2,sp2s p^3, s p^2, s p^2

Correct answer

A. sp2,sp2,sp3s p^2, s p^2, s p^3

Step-by-step solution

C˙H3\dot{\mathrm{C}} \mathrm{H}_3 (methyl free radical) has planar structure with sp2s p^2 hybridisation of ' C\mathrm{C} ' atom. The odd electron is present in unhybridised 2pz2 p_z orbital. ⊕CH3\oplus \mathrm{CH}_3 (methyl carbonium ion) has also trigonal planar structure \left(s p^2\right)..\stackrel{\ominus}{\mathrm{CH}_3}(methylcarbanion)hastetrahedralstructure(sp3)(methyl carbanion) has tetrahedral structure \left(s p^3\right) and one of the hybrid orbitals contains the lone pair of electrons.
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