AIIMS 2002
- Exam
- AIIMS
- Year
- 2002
- Subject
- Chemistry
- Chapter
- Chemical Bonding and Molecular Structure
AIIMS 2002 · Chemistry · Chemical Bonding and Molecular Structure
Assertion : Sigma ( σ is a strong bond, while pi (π) is a weak...
Assertion : Sigma ( is a strong bond, while pi is a weak bond.
Reason : Atoms rotate freely about pi ( ) bond.
Options
- AIf both the assertion and reason are true and reason is a correct explanation of the assertion.
- BIf both assertion and reason are true but assertion is not a correct explanation of the assertion.
- CIf the assertion is true but the reason is false.
- DIf both assertion and reason are false.
Correct answer
C. If the assertion is true but the reason is false.
Step-by-step solution
Sigma bonding involves end to end overlapping of the two atomic orbitals e.g. between and and and and orbitals.
Pi bonding involves sidewise overlapping of the two atomic orbitals e.g. between and orbitals.
Overlapping of orbitals is more effective in bonding than in -bonding. Due to the geometry of overlapping or orbitals, rotation of one atom is not

possible around -bonds.
possible around -bonds.