Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
AIIMS 2013
Exam
AIIMS
Year
2013
Subject
Chemistry
Chapter
Coordination Compounds

AIIMS 2013 · Chemistry · Coordination Compounds

Assertion : Aq. solution of CoCl_2 is pink in colour. It turns blue...

Assertion : Aq. solution of CoCl2\mathrm{CoCl}_2 is pink in colour. It turns blue in presence of conc. HCl\mathrm{HCl}. Reason : It is due to the formation of \left[\mathrm{CoCl}_4\right]^{2-}.

Options

  1. AIf both assertion and reason are true and reason is the correct explanation of assertion.
  2. BIf both assertion and reason are true but reason is not the correct explanation of assertion.
  3. CIf assertion is true but reason is false.
  4. DIf both assertion and reason are false.

Correct answer

A. If both assertion and reason are true and reason is the correct explanation of assertion.

Step-by-step solution

[Co(H2O)6]2++4Cl−⇌[CoCl4]2−+6H2O\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}+4 \mathrm{Cl}^{-} \rightleftharpoons\left[\mathrm{CoCl}_4\right]^{2-}+6 \mathrm{H}_2 \mathrm{O} Pink Blue According to Le Chatelier's principle, on adding conc. HCl\mathrm{HCl}, the equilibrium shifts in forward direction giving blue colour. And when this blue colour is diluted, equilibrium shifts in backward direction leading to pink colour.
Practice Coordination Compounds on Quantrex Academy →

More from Coordination Compounds

[Ti(H_2O)_6]^ 2+ is a colored compound where as [Zn(H_2O)_6]^ 2+ is colorless, because MHT CET Medical 2026What is coordination number of central metal ion in cisplatin ? MHT CET Medical 2026Which of the following complexes exhibits solvate isomerism? MHT CET Medical 2026What type of ligand the ethylenediamine is? MHT CET Medical 2026Which of the following isomers is used in the treatment of cancer? MHT CET Medical 2026Identify the geometry and magnetic behavior of the complex [Ni(CO)_4] . MHT CET Medical 2026Identify the correct match from the following for coordinate complex (column A) and… MHT CET Medical 2026Which type of complex is Diamminedichloroplatinum(II)? MHT CET Medical 2026 Full Coordination Compounds list All AIIMS PYQs