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AIIMS 2003
Exam
AIIMS
Year
2003
Subject
Chemistry
Chapter
Coordination Compounds

AIIMS 2003 · Chemistry · Coordination Compounds

Assertion: NF_3 is a weaker ligand than N(CH_3)_3 . Reason : NF_3...

Assertion: NF3\mathrm{NF}_3 is a weaker ligand than N(CH3)3\mathrm{N}\left(\mathrm{CH}_3\right)_3. Reason : NF3\mathrm{NF}_3 ionizes to give F−\mathrm{F}^{-}ions in aqueous solution.Assertion: NF_3 is a weaker ligand than N(CH_3)_3 . Reason : NF_3 ionizes to give F^ - ions in aqueous solution.

Options

  1. AIf both assertion and reason are true and the reason is the correct explanation of the assertion
  2. BIf both assertion and reason are true and the reason is not the correct explanation of the assertion
  3. CIf assertion is true but reason is false
  4. DIf both assertion and reason are false.

Correct answer

C. If assertion is true but reason is false

Step-by-step solution

Due to high electronegativity of F-atoms, the lone pair of N\mathrm{N}-atom in NF3\mathrm{NF}_3 molecule cannot be ligated easily. Assertion: NF_3 is a weaker ligand than N(CH_3)_3 . Reason : NF_3 ionizes to give F^ - ions in aqueous solution.
Except, nitrogen fluoride, all other halides hydrolyse in water. NCl3+3H2O→NH3+3HClO. \mathrm{NCl}_3+3 \mathrm{H}_2 \mathrm{O} \rightarrow \mathrm{NH}_3+3 \mathrm{HClO} \text{. }
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