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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

Identify the processes in which the entropy of the system...

Identify the processes in which the entropy of the system decreases.
A. Freezing of water to ice at 273 K273 \text{ K}.
B. 2SO2(g)+O2(g)→2SO3(g)2\mathrm{SO}_{2(\mathrm{g})} + \mathrm{O}_{2(\mathrm{g})} \rightarrow 2\mathrm{SO}_{3(\mathrm{g})}
C. Mixing of two non-reacting ideal gases at constant temperature.
D. Dissolution of oxygen gas in water.
Choose the correct answer from the options given below:

Options

  1. AA, C and D
  2. BB, C and D
  3. CA and B only
  4. DA, B and D

Correct answer

D. A, B and D

Step-by-step solution

A. Freezing of water to ice at 273 K273 \text{ K}: The process involves the conversion of a liquid to a solid. The molecules become more ordered, so the entropy of the system decreases (ΔS<0\Delta S < 0).

B. 2SO2(g)+O2(g)→2SO3(g)2\mathrm{SO}_{2(\mathrm{g})} + \mathrm{O}_{2(\mathrm{g})} \rightarrow 2\mathrm{SO}_{3(\mathrm{g})}: The number of moles of gaseous species decreases from 33 to 22. This leads to a decrease in randomness, so the entropy decreases (ΔS<0\Delta S < 0).

C. Mixing of two non-reacting ideal gases at constant temperature: The volume available for each gas increases, leading to an increase in randomness. Thus, the entropy of the system increases (ΔS>0\Delta S > 0).

D. Dissolution of oxygen gas in water: The gaseous oxygen molecules lose their freedom of movement when they dissolve in a liquid solvent. This results in a decrease in randomness, so the entropy decreases (ΔS<0\Delta S < 0).

Therefore, the entropy of the system decreases in processes A, B, and D.

Answer: A, B and D
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