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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

Consider the five cyclic species (I to V) shown in the figure....

Consider the five cyclic species (I to V) shown in the figure. According to Huckel's rule, how many of these species
Consider the five cyclic species (I to V) shown in the figure.

According to Huckel's rule, how many of these species are aromatic?

Options

  1. A1
  2. B2
  3. C3
  4. D4

Correct answer

C. 3

Step-by-step solution

According to Huckel's rule, a species is aromatic if it is cyclic, planar, fully conjugated, and contains (4n+2)(4n + 2) π\pi electrons, where nn is an integer (0,1,2,…0, 1, 2, \dots).

(I) Naphthalene: It is a planar, fully conjugated bicyclic system with 55 double bonds, giving 1010 π\pi electrons. Since 10=4(2)+210 = 4(2) + 2, it is aromatic.

(II) Cyclopentadienyl cation: It is a planar, fully conjugated cyclic system with 22 double bonds, giving 44 π\pi electrons. Since 4=4(1)4 = 4(1), it is antiaromatic.

(III) Pyrrole: It is a planar, fully conjugated cyclic system. The nitrogen atom contributes its lone pair to the π\pi system. Total π\pi electrons = 44 (from double bonds) + 22 (from lone pair) = 66. Since 6=4(1)+26 = 4(1) + 2, it is aromatic.

(IV) Cyclopropenyl anion: It is a planar, fully conjugated cyclic system. The negative charge contributes 22 electrons to the π\pi system. Total π\pi electrons = 22 (from double bond) + 22 (from negative charge) = 44. Since 4=4(1)4 = 4(1), it is antiaromatic.

(V) Thiophene: It is a planar, fully conjugated cyclic system. The sulfur atom contributes one of its lone pairs to the π\pi system. Total π\pi electrons = 44 (from double bonds) + 22 (from lone pair) = 66. Since 6=4(1)+26 = 4(1) + 2, it is aromatic.

Therefore, the aromatic species are (I), (III), and (V). There are 33 aromatic species in total.

Answer: 3
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