NEET 2026
- Exam
- NEET
- Year
- 2026
- Subject
- Chemistry
- Chapter
- Chapter
NEET 2026 · Chemistry · Chapter
Consider the five cyclic species (I to V) shown in the figure....
Consider the five cyclic species (I to V) shown in the figure.
According to Huckel's rule, how many of these species are aromatic?
Options
- A1
- B2
- C3
- D4
Correct answer
C. 3
Step-by-step solution
According to Huckel's rule, a species is aromatic if it is cyclic, planar, fully conjugated, and contains electrons, where is an integer ().
(I) Naphthalene: It is a planar, fully conjugated bicyclic system with double bonds, giving electrons. Since , it is aromatic.
(II) Cyclopentadienyl cation: It is a planar, fully conjugated cyclic system with double bonds, giving electrons. Since , it is antiaromatic.
(III) Pyrrole: It is a planar, fully conjugated cyclic system. The nitrogen atom contributes its lone pair to the system. Total electrons = (from double bonds) + (from lone pair) = . Since , it is aromatic.
(IV) Cyclopropenyl anion: It is a planar, fully conjugated cyclic system. The negative charge contributes electrons to the system. Total electrons = (from double bond) + (from negative charge) = . Since , it is antiaromatic.
(V) Thiophene: It is a planar, fully conjugated cyclic system. The sulfur atom contributes one of its lone pairs to the system. Total electrons = (from double bonds) + (from lone pair) = . Since , it is aromatic.
Therefore, the aromatic species are (I), (III), and (V). There are aromatic species in total.
Answer: 3
(I) Naphthalene: It is a planar, fully conjugated bicyclic system with double bonds, giving electrons. Since , it is aromatic.
(II) Cyclopentadienyl cation: It is a planar, fully conjugated cyclic system with double bonds, giving electrons. Since , it is antiaromatic.
(III) Pyrrole: It is a planar, fully conjugated cyclic system. The nitrogen atom contributes its lone pair to the system. Total electrons = (from double bonds) + (from lone pair) = . Since , it is aromatic.
(IV) Cyclopropenyl anion: It is a planar, fully conjugated cyclic system. The negative charge contributes electrons to the system. Total electrons = (from double bond) + (from negative charge) = . Since , it is antiaromatic.
(V) Thiophene: It is a planar, fully conjugated cyclic system. The sulfur atom contributes one of its lone pairs to the system. Total electrons = (from double bonds) + (from lone pair) = . Since , it is aromatic.
Therefore, the aromatic species are (I), (III), and (V). There are aromatic species in total.
Answer: 3