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JEE Main
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Chemistry
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Practical Chemistry

JEE Main · Chemistry · Practical Chemistry

An aqueous solution of a lead(II) salt is divided into two test...

An aqueous solution of a lead(II) salt is divided into two test tubes. Addition of potassium iodide to the first test tube produces a yellow precipitate 'X' which dissolves in boiling water and recrystallizes on cooling. Addition of potassium chromate to the second test tube produces a yellow precipitate 'Y' which is insoluble in acetic acid.

The chemical identities of precipitates X and Y respectively are:

Options

  1. AX = PbCrO4PbCrO_4, Y = PbI2PbI_2
  2. BX = AgIAgI, Y = BaCrO4BaCrO_4
  3. CX = PbI2PbI_2, Y = PbCrO4PbCrO_4
  4. DX = PbI4PbI_4, Y = Pb(CrO4)2Pb(CrO_4)_2

Correct answer

C. X = PbI2PbI_2, Y = PbCrO4PbCrO_4

Step-by-step solution

The reaction of Pb2+Pb^{2+} with KIKI yields a yellow precipitate of lead iodide (PbI2PbI_2). A unique characteristic of PbI2PbI_2 is that it dissolves in boiling water to give a colorless solution and recrystallizes as golden spangles upon cooling.

The reaction of Pb2+Pb^{2+} with K2CrO4K_2CrO_4 yields a yellow precipitate of lead chromate (PbCrO4PbCrO_4), which is insoluble in acetic acid but soluble in sodium hydroxide.

Thus, X is PbI2PbI_2 and Y is PbCrO4PbCrO_4.

Answer: X = PbI2PbI_2, Y = PbCrO4PbCrO_4
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