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JEE Main
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Chemistry
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Solid State

JEE Main · Chemistry · Solid State

A certain metal with a molar mass of 48 g/mol crystallizes in a...

A certain metal with a molar mass of 48 g/mol48 \text{ g/mol} crystallizes in a cubic lattice. The density of the metal is 20 g/cm320 \text{ g/cm}^3 and the edge length of its unit cell is 200 pm200 \text{ pm}. The coordination number of the metal atom in this crystal lattice is ___ .
(Given: Avogadro's number NA=6×1023 mol−1N_A = 6 \times 10^{23} \text{ mol}^{-1})

Correct answer

8

Step-by-step solution

The formula for the density of a cubic unit cell is:
d=Z×MNA×a3d = \dfrac{Z \times M}{N_A \times a^3}

Given:
d=20 g/cm3d = 20 \text{ g/cm}^3
M=48 g/molM = 48 \text{ g/mol}
NA=6×1023 mol−1N_A = 6 \times 10^{23} \text{ mol}^{-1}
a=200 pm=2×10−8 cma = 200 \text{ pm} = 2 \times 10^{-8} \text{ cm}

Volume of the unit cell, a3=(2×10−8)3=8×10−24 cm3a^3 = (2 \times 10^{-8})^3 = 8 \times 10^{-24} \text{ cm}^3

Rearranging the density formula to solve for the number of atoms per unit cell (ZZ):
Z=d×NA×a3MZ = \dfrac{d \times N_A \times a^3}{M}
Z=20×6×1023×8×10−2448Z = \dfrac{20 \times 6 \times 10^{23} \times 8 \times 10^{-24}}{48}
Z=20×48×10−148=2Z = \dfrac{20 \times 48 \times 10^{-1}}{48} = 2

Since Z=2Z = 2, the metal crystallizes in a body-centered cubic (BCC) lattice.
The coordination number of an atom in a BCC lattice is 88.

Answer: 88
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