Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE MainChemistryd and f Block Elements

A black-coloured oxide (A) of a 3d transition metal, when heated in a stream of dihydrogen gas, yields a reddish-brown metal (B) and a colourless liquid. The spin-only magnetic moment of the metal ion in the oxide (A) is:

Options

  1. A0 BM
  2. B2.83 BM
  3. C1.73 BM
  4. D3.87 BM

Correct answer

C. 1.73 BM

Step-by-step solution

The reddish-brown metal (B) obtained by the reduction of the oxide with dihydrogen is copper ( Cu ). The colourless liquid is water ( H ₂ O ). The black-coloured oxide (A) of copper is copper(II) oxide ( CuO ). In CuO , the oxidation state of copper is +2 . The electronic configuration of neutral Cu is [ Ar ] 3 d ¹⁰ 4 s ^1 . The electronic configuration of Cu ²⁺ is [ Ar ] 3 d ^9 . The 3 d ^9 configuration has 1 unpaired electron ( n = 1 ). The spin-only magnetic moment ( ) is given by: = n(n+2) BM = 1(1+2) = 3 1.73

Practice d and f Block Elements on Quantrex Academy →

More from d and f Block Elements

Given below are two statements: Statement I: The number of pairs among [ Ti ⁴⁺, V ²⁺] , [ V ²⁺, Mn ²⁺] , [ Mn ²⁺, Fe ³⁺] and [ V ²⁺, Cr ²⁺] in which both ions are coloured is 3 . S 2026Given below are two statements for catalytic properties of transition metals. Statement I: First row transition metals which act as catalyst utilise their 3d electrons only for 2026The correct order of first ( _i H₁) and second ( _i H₂) ionisation enthalpy values of Cr and Mn are : A. _i H₁ : Cr > Mn B. _i H₂ : Cr > Mn C. _i H₁ : Mn > Cr D. _i H₂ : Mn > Cr Ch 2026The correct statements among the following are. A. Basic vanadium oxide is used in the manufacture of H ₂ SO ₄ . B. The spin-only magnetic moment value of the transition metal hali 2026Given below are two statements : Statement I: Presence of large number of unpaired electrons in transition metal atoms results in higher enthalpies of their atomisation. Statement 2026A paper dipped in a dil. H₂SO₄ solution of ' X ' upon treatment with SO₂ gas turns into green. The compound ' X ' is : 2026Which of the following is NOT a physical or chemical characteristics of interstitial compounds? 2026Pairs of elements with the same number of electrons in their respective 4f orbital are [Atomic number. Eu-63, Gd-64, Dy-66, Ho-67, Tm-69, Yb-70, Lu-71, Hf-72] A. (Eu and Gd) B. (Dy 2026 Full d and f Block Elements list All JEE Main PYQs