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- JEE Main
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- Practical Chemistry
JEE Main · Chemistry · Practical Chemistry
A student is given an aqueous mixture containing Fe^ 3+ and Mg^ 2+...
A student is given an aqueous mixture containing and ions. Upon adding solid followed by excess solution, a brown precipitate forms, but remains in the solution. The combined thermodynamic and equilibrium reason why does not precipitate under these specific conditions is that :
Options
- Athe common ion effect of keeps low, which fails to exceed the higher of
- B has a lower than , preventing its precipitation in basic medium
- Cthe common ion effect of suppresses the dissociation of the mixture, preventing the precipitation of
- D forms a highly soluble ammine complex with excess ammonia
Correct answer
A. the common ion effect of keeps low, which fails to exceed the higher of
Step-by-step solution
Ammonium hydroxide () is a weak base, and its ionization is suppressed by the addition of the strong electrolyte ammonium chloride () due to the common ion effect of ions.
This suppression keeps the concentration of ions very low in the solution. The solubility product () is much lower (around ) compared to that of (around ). The low is sufficient to make the ionic product of exceed its , leading to its precipitation. However, the ionic product of does not exceed its relatively higher , so remains dissolved in the solution.
Answer: the common ion effect of keeps low, which fails to exceed the higher of
This suppression keeps the concentration of ions very low in the solution. The solubility product () is much lower (around ) compared to that of (around ). The low is sufficient to make the ionic product of exceed its , leading to its precipitation. However, the ionic product of does not exceed its relatively higher , so remains dissolved in the solution.
Answer: the common ion effect of keeps low, which fails to exceed the higher of