JEE Main
- Exam
- JEE Main
- Subject
- Chemistry
- Chapter
- Practical Chemistry
JEE Main · Chemistry · Practical Chemistry
An aqueous solution of an unknown inorganic salt is treated with...
An aqueous solution of an unknown inorganic salt is treated with solid and an aqueous solution of . Upon subsequent addition of an aqueous solution of , a white precipitate is formed. Which of the following cations is most likely present in the solution?
Options
- A
- B
- C
- D
Correct answer
D.
Step-by-step solution
The reagent mixture of , , and is the group reagent for Group V cations in systematic qualitative analysis.
The Group V cations include , , and . They precipitate as their respective insoluble carbonates (e.g., ).
belongs to Group VI and does not precipitate here because the presence of suppresses the ionization of , keeping the carbonate ion concentration too low to exceed the solubility product of .
(Group IV) (Group II) precipitate with different group reagents. Therefore, the cation present is .
Answer:
The Group V cations include , , and . They precipitate as their respective insoluble carbonates (e.g., ).
belongs to Group VI and does not precipitate here because the presence of suppresses the ionization of , keeping the carbonate ion concentration too low to exceed the solubility product of .
(Group IV) (Group II) precipitate with different group reagents. Therefore, the cation present is .
Answer: