JEE Main
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- JEE Main
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- Chemistry
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- Practical Chemistry
JEE Main · Chemistry · Practical Chemistry
In the qualitative analysis of Group II cations, hydrogen sulfide (...
In the qualitative analysis of Group II cations, hydrogen sulfide () gas is passed through the original solution in the presence of dilute hydrochloric acid (). The primary chemical reason for adding dilute before passing gas is to :
Options
- Aincrease the concentration of ions for faster precipitation
- Bincrease the concentration of ions to form soluble chloride complexes
- Cdissolve any interfering phosphate ions present in the mixture
- Ddecrease the concentration of ions by common ion effect
Correct answer
D. decrease the concentration of ions by common ion effect
Step-by-step solution
is a strong acid that completely dissociates to give and ions.
Hydrogen sulfide () is a weak diprotic acid that ionizes as:
The presence of ions from suppresses the ionization of due to the common ion effect. This significantly decreases the concentration of ions in the solution. The reduced is sufficient to exceed the extremely low solubility product () of Group II sulfides, but it is too low to precipitate Group IV sulfides, thereby ensuring selective precipitation.
Answer: decrease the concentration of ions by common ion effect
Hydrogen sulfide () is a weak diprotic acid that ionizes as:
The presence of ions from suppresses the ionization of due to the common ion effect. This significantly decreases the concentration of ions in the solution. The reduced is sufficient to exceed the extremely low solubility product () of Group II sulfides, but it is too low to precipitate Group IV sulfides, thereby ensuring selective precipitation.
Answer: decrease the concentration of ions by common ion effect