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JEE MainChemistryd and f Block Elements

Consider the following statements regarding the elements of Group 12 ( Zn , Cd , and Hg ): I. While Zn and Cd are solids, Hg is a liquid at room temperature due to its high ionization enthalpy and weak metallic bonding. II. Zn and Cd have negative standard reduction potentials ( E^ _ M ²⁺/ M ), whereas Hg has a positive standard reduction potential. III. Hg can form dimeric ions in the +1 oxidation state, but Zn and

Options

  1. AI, II, III and IV
  2. BI, II and III only
  3. CII and III only
  4. DI and III only

Correct answer

B. I, II and III only

Step-by-step solution

Statement I is correct: Mercury is a liquid at room temperature because its 6s electrons are tightly bound, leading to a high ionization enthalpy and very weak metallic bonding. Statement II is correct: The standard reduction potentials ( E^ _ M ²⁺/ M ) for Zn and Cd are negative ( -0.76 V and -0.40 V respectively), making them reactive metals, whereas Hg has a positive value ( +0.85 V ), making it less reactive. Statement III is correct: Mercury can exhibit a +1 oxidation state by forming the dimeric ion Hg ₂²⁺ ,

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