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MHT CET 202621 AprilMorning Shift
Exam
MHT CET
Year
2026
Date
21 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Aldehydes and Ketones

MHT CET 2026 · 21 April · Morning Shift · Chemistry · Aldehydes and Ketones

Identify a catalyst used in Stephen reaction from the following.

Identify a catalyst used in Stephen reaction from the following.

Options

  1. AZnCl2\text{ZnCl}_2 and HCl
  2. BHgCl2\text{HgCl}_2 and HCl
  3. CSnCl2\text{SnCl}_2 and HCl
  4. DAgCl and HCl

Correct answer

C. SnCl2\text{SnCl}_2 and HCl

Step-by-step solution

The Stephen reaction involves the reduction of an alkyl cyanide (nitrile) to the corresponding aldehyde.

The reagents used in this reaction are stannous chloride (SnCl2\text{SnCl}_2) and hydrochloric acid (HCl\text{HCl}).

The reaction proceeds via the formation of an imine hydrochloride intermediate, which upon hydrolysis yields the aldehyde.

R−C≡N+SnCl2+HCl→R−CH=NH⋅HCl→H3O+R−CHO+NH4+R-C \equiv N + \text{SnCl}_2 + \text{HCl} \rightarrow R-CH=NH \cdot \text{HCl} \xrightarrow{H_3O^+} R-CHO + \text{NH}_4^+

Therefore, the correct catalyst/reagent is SnCl2\text{SnCl}_2 and HCl\text{HCl}.

Answer: SnCl2\text{SnCl}_2 and HCl
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