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MHT CET Medical202621 April 2026Morning ShiftChemistryCoordination CompoundsActual

What quantity of AgCl is precipitated when one mole of Pentaamminecarbonatocobalt(III) chloride is treated with excess AgNO ₃ (molar mass = 143.3 g mol ⁻¹ ) solution?

Options

  1. A143.3 g
  2. B72.0 g
  3. C286.6 g
  4. D215.0 g

Correct answer

A. 143.3 g

Step-by-step solution

The formula of pentaamminecarbonatocobalt(III) chloride is [ Co ( NH ₃)₅( CO ₃)] Cl . In this complex, there is one ionizable chloride ion present outside the coordination sphere. When one mole of this complex is treated with excess AgNO ₃ solution, it yields one mole of AgCl precipitate. [ Co ( NH ₃)₅( CO ₃)] Cl + AgNO ₃ [ Co ( NH ₃)₅( CO ₃)] NO ₃ + AgCl Mass of one mole of AgCl = 143.3 g . Therefore, 143.3 g of AgCl is precipitated. Answer: 143.3 g

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