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MHT CET 202625 AprilMorning Shift
Exam
MHT CET
Year
2026
Date
25 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Coordination Compounds

MHT CET 2026 · 25 April · Morning Shift · Chemistry · Coordination Compounds

Identify the geometry of a complex compound [CoF_6]^ -3 .

Identify the geometry of a complex compound [CoF6]−3[\text{CoF}_6]^{-3}.

Options

  1. ASquare planar
  2. BTetrahedral
  3. COctahedral
  4. DTrigonal pyramidal

Correct answer

C. Octahedral

Step-by-step solution

The given complex is [CoF6]3−[\text{CoF}_6]^{3-}.

The central metal atom is Cobalt (Co). Let its oxidation state be xx.

x+6(−1)=−3⇒x=+3x + 6(-1) = -3 \Rightarrow x = +3

The electronic configuration of Co is [Ar]3d74s2[\text{Ar}] 3d^7 4s^2.

The electronic configuration of Co^{3+}isis[Ar\text{Ar}] 3d^6.<br><br>SinceF−.<br><br>Since F^- is a weak field ligand, it does not cause pairing of electrons in the 3d3d orbitals.

The complex undergoes sp3d2sp^3d^2 hybridization to accommodate six F^- ligands.

For a coordination number of 6, the geometry of the complex is octahedral.

Answer: Octahedral
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