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MHT CET 202623 AprilEvening Shift
Exam
MHT CET
Year
2026
Date
23 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Hydrocarbons

MHT CET 2026 · 23 April · Evening Shift · Chemistry · Hydrocarbons

What is the major product obtained by oxidation of phenylethene...

What is the major product obtained by oxidation of phenylethene with KMnO4\text{KMnO}_4 in dilute H2SO4\text{H}_2\text{SO}_4?

Options

  1. ABenzoic acid
  2. BEthylene glycol
  3. CAcetophenone
  4. DBenzophenone

Correct answer

A. Benzoic acid

Step-by-step solution

Phenylethene (styrene) has the structure C6H5CH=CH2\text{C}_6\text{H}_5\text{CH}=\text{CH}_2.

When treated with a strong oxidizing agent like KMnO4\text{KMnO}_4 in an acidic medium (dilute H2SO4\text{H}_2\text{SO}_4), oxidative cleavage of the carbon-carbon double bond takes place.

The terminal =CH2=\text{CH}_2 group is oxidized to CO2\text{CO}_2 and H2O\text{H}_2\text{O}.

The C6H5CH=\text{C}_6\text{H}_5\text{CH}= group is oxidized to a carboxylic acid, yielding benzoic acid (C6H5COOH\text{C}_6\text{H}_5\text{COOH}).

The reaction is given by:
C6H5CH=CH2→KMnO4,H+C6H5COOH+CO2+H2O\text{C}_6\text{H}_5\text{CH}=\text{CH}_2 \xrightarrow{\text{KMnO}_4, \text{H}^+} \text{C}_6\text{H}_5\text{COOH} + \text{CO}_2 + \text{H}_2\text{O}

Thus, the major product obtained is benzoic acid.

Answer: Benzoic acid
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