NEET 2024
- Exam
- NEET
- Year
- 2024
- Subject
- Chemistry
- Chapter
- Coordination Compounds
NEET 2024 · Chemistry · Coordination Compounds
Given below are two statements : Statement I: Both [Co(NH_3)_6]^ 3+...
Given below are two statements :
Statement I: Both and \left[\mathrm{CoF}_6\right]^{3-}\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+} is paramagnetic.
In the light of the above statements, choose the correct answer from the options given below:![Given below are two statements : Statement I: Both [Co(NH_3)_6]^ 3+ and [CoF_6]^ 3- complexes are octahedral but differ](/api/proxy-image?clean=1&b=aHR0cHM6Ly9jZG4tcXVlc3Rpb24tcG9vbC5nZXRtYXJrcy5hcHAvcHlxL25lZXQvZFctaWtMYUgya0g0N3QxQjdvVlJtcUJMYmdVZEloQTBxQUJzWkpVZGdBUS5vcmlnaW5hbC5mdWxsc2l6ZS5wbmc)
![Given below are two statements : Statement I: Both [Co(NH_3)_6]^ 3+ and [CoF_6]^ 3- complexes are octahedral but differ](/api/proxy-image?clean=1&b=aHR0cHM6Ly9jZG4tcXVlc3Rpb24tcG9vbC5nZXRtYXJrcy5hcHAvcHlxL25lZXQvTkU4Vm5WSzI3LVphanAxWEZoVWJHbnc3LWRvOVg4c2swMEZZNGRmT2tNby5vcmlnaW5hbC5mdWxsc2l6ZS5wbmc)
![Given below are two statements : Statement I: Both [Co(NH_3)_6]^ 3+ and [CoF_6]^ 3- complexes are octahedral but differ](/api/proxy-image?clean=1&b=aHR0cHM6Ly9jZG4tcXVlc3Rpb24tcG9vbC5nZXRtYXJrcy5hcHAvcHlxL25lZXQvZDZPSkM5amZtQlNmaUZ5UjFyeHJoX05jV2R3bFczLXhfeU9IYkdnNEFNby5vcmlnaW5hbC5mdWxsc2l6ZS5wbmc)
Options
- ABoth Statement I and Statement II are false
- BStatement I is true but Statement II is false
- CStatement I is false but Statement II is true
- DBoth Statement I and Statement II are true
Correct answer
D. Both Statement I and Statement II are true
Step-by-step solution
In ion is having configuration.
Electronic configuration of :
![Given below are two statements : Statement I: Both [Co(NH_3)_6]^ 3+ and [CoF_6]^ 3- complexes are octahedral but differ](/api/proxy-image?clean=1&b=aHR0cHM6Ly9jZG4tcXVlc3Rpb24tcG9vbC5nZXRtYXJrcy5hcHAvcHlxL25lZXQvZFctaWtMYUgya0g0N3QxQjdvVlJtcUJMYmdVZEloQTBxQUJzWkpVZGdBUS5vcmlnaW5hbC5mdWxsc2l6ZS5wbmc)
In presence of ligand, pairing of electrons takes place and it becomes diamagnetic complex ion. In presence of ligand :![Given below are two statements : Statement I: Both [Co(NH_3)_6]^ 3+ and [CoF_6]^ 3- complexes are octahedral but differ](/api/proxy-image?clean=1&b=aHR0cHM6Ly9jZG4tcXVlc3Rpb24tcG9vbC5nZXRtYXJrcy5hcHAvcHlxL25lZXQvTkU4Vm5WSzI3LVphanAxWEZoVWJHbnc3LWRvOVg4c2swMEZZNGRmT2tNby5vcmlnaW5hbC5mdWxsc2l6ZS5wbmc)
\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+} is octahedral with hybridisation and it is diamagnetic in nature. In case of \left[\mathrm{CoF}_6\right]^{3-}3 \mathrm{~d}^6\mathrm{F}^{-}\mathrm{F}^{-}\therefore is hybridised with four unpaired electrons, so it is paramagnetic in nature.
In presence of ligand, pairing of electrons takes place and it becomes diamagnetic complex ion. In presence of ligand :
\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+} is octahedral with hybridisation and it is diamagnetic in nature. In case of \left[\mathrm{CoF}_6\right]^{3-}3 \mathrm{~d}^6\mathrm{F}^{-}\mathrm{F}^{-}\therefore is hybridised with four unpaired electrons, so it is paramagnetic in nature.