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NEET 2022
Exam
NEET
Year
2022
Subject
Chemistry
Chapter
Coordination Compounds

NEET 2022 · Chemistry · Coordination Compounds

Given below are two statements: one is labelled as Assertion (A)...

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): The metal carbon bond in metal carbonyls possesses both σ\sigma and π\pi character. Reason (R): The ligand to metal bond is a π\pi bond and metal to ligand bond is a σ\sigma bond. In the light of the above statements, choose the most appropriate answer from the options given below:Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion

Options

  1. ABoth (A) and (R) are correct and (R) is the correct explanation of (A)
  2. BBoth (A) and (R) are correct but (R) is not the correct explanation of (A)
  3. C(A) is correct but (R)(\mathrm{R}) is not correct.
  4. D(A) is not correct but (R) is correct.

Correct answer

C. (A) is correct but (R)(\mathrm{R}) is not correct.

Step-by-step solution

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion
In case of metal carbonyls, the bonding has both (\sigma) and (\pi) nature, where ligand to metal bond is ' (\sigma) ' (coordinate) bond and metal to ligand bond is ' (\pi) ' (synergic) bond.
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