NEET2022ChemistryCoordination CompoundsActual
The order of energy absorbed which is responsible for the color of complexes (A) Ni H 2 O 2 ( en ) 2 2 + (B) Ni H 2 O 4 ( en ) 2 + and (C) Ni ( en ) 3 2 + is
Options
- A( C ) > ( B ) > ( A )
- B( C ) > ( A ) > ( B )
- C( B ) > ( A ) > ( C )
- D( A ) > ( B ) > ( C )
Correct answer
B. ( C ) > ( A ) > ( B )
Step-by-step solution
The complexes with strong filed ligands absorbs the highest energy light than complexes with weak field ligands. Ethylene diamine(en) is strong field ligand and H 2 O is the weak field ligand. Hence, the correct order of energy absorbed is Ni en 3 2 + > Ni H 2 O 2 en 2 2 + > Ni H 2 O 4 en 2 +