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NEET 2016
Exam
NEET
Year
2016
Subject
Chemistry
Chapter
Coordination Compounds

NEET 2016 · Chemistry · Coordination Compounds

Jahn-Teller effect is not observed in high spin complexes of

Jahn-Teller effect is not observed in high spin complexes of

Options

  1. Ad7{d}^{7}
  2. Bd8{d}^{8}
  3. Cd4{d}^{4}
  4. Dd9{d}^{9}

Correct answer

B. d8{d}^{8}

Step-by-step solution

Jahn Teller effect (JTE) explains the axial distortion in perfect octahedral geometry. It is present in d4{d}^{4} high spin, d7{d}^{7} low spin and d9{d}^{9} configuration, which have an odd number of electrons in a eg{e}_{g} set. A weak Jahn Teller effect is also present in d7{d}^{7} high spin complex, which has an odd number of electrons in the set. Therefore, the Jahn Teller effect is not observed in high spin complexes of d8{d}^{8} orbital.
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