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NEET 2012
Exam
NEET
Year
2012
Subject
Chemistry
Chapter
Coordination Compounds

NEET 2012 · Chemistry · Coordination Compounds

Low spin complex of d^6 -cation in an octahedral field will have...

Low spin complex of d6d^6-cation in an octahedral field will have the following energy (Δo=\left(\Delta_o=\right. crystal field splitting energy in an octahedral field, P=P= electron pairing energy)

Options

  1. A−125Δo+P\frac{-12}{5} \Delta_o+P
  2. B−125Δo+3P\frac{-12}{5} \Delta_o+3 P
  3. C−25Δo+2P\frac{-2}{5} \Delta_o+2 P
  4. D−25Δo+P\frac{-2}{5} \Delta_o+P

Correct answer

B. −125Δo+3P\frac{-12}{5} \Delta_o+3 P

Step-by-step solution

(\text{C.F.S.E. }=(-0.4 x+0.6 y) \Delta_o+z P) where (\mathrm{x}=) number of electrons occupying (\mathrm{t}_{2 g}) orbital y=y= number of electrons occupying ege_g orbital z=z= number of pairs of electrons For low spin (\mathrm{d}^6) complex electronic configuration =t2g6eg0 or t2g2,2,2eg0∴x=6,y=0,z=3 C.F.S.E. =(−0.4×6+0×0.6)Δo+3P=−125Δo+3P\begin{aligned} & =t_{2 g}^6 e_g^0 \text{ or } t_{2 g}^{2,2,2} e_g^0 \\ & \therefore \quad x=6, y=0, z=3 \\ & \text{ C.F.S.E. }=(-0.4 \times 6+0 \times 0.6) \Delta_o+3 P \\ & =\frac{-12}{5} \Delta_o+3 P \end{aligned})$
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