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NEET 2011
Exam
NEET
Year
2011
Subject
Chemistry
Chapter
Coordination Compounds

NEET 2011 · Chemistry · Coordination Compounds

Which of the following complex compounds will exhibit highest...

Which of the following complex compounds will exhibit highest paramagnetic behaviour? (At. no. : Ti=22,Cr=24\mathrm{Ti}=22, \mathrm{Cr}=24, Co=27,Zn=30\mathrm{Co}=27, \mathrm{Zn}=30 )Which of the following complex compounds will exhibit highest paramagnetic behaviour? (At. no. : Ti=22, Cr=24 , Co=27,Which of the following complex compounds will exhibit highest paramagnetic behaviour? (At. no. : Ti=22, Cr=24 , Co=27,Which of the following complex compounds will exhibit highest paramagnetic behaviour? (At. no. : Ti=22, Cr=24 , Co=27,Which of the following complex compounds will exhibit highest paramagnetic behaviour? (At. no. : Ti=22, Cr=24 , Co=27,Which of the following complex compounds will exhibit highest paramagnetic behaviour? (At. no. : Ti=22, Cr=24 , Co=27,Which of the following complex compounds will exhibit highest paramagnetic behaviour? (At. no. : Ti=22, Cr=24 , Co=27,

Options

  1. A\left[\mathrm{Ti}\left(\mathrm{NH}_3\right)_6\right]^{3+}
  2. B\left[\mathrm{Cr}\left(\mathrm{NH}_3\right)_6\right]^{3+}
  3. C\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}
  4. D\left[\mathrm{Zn}\left(\mathrm{NH}_3\right)_6\right]^{2+}

Correct answer

B. \left[\mathrm{Cr}\left(\mathrm{NH}_3\right)_6\right]^{3+}

Step-by-step solution

(A) Electronic configuration of \mathrm{Ti}^{3+} in \left[\mathrm{Ti}\left(\mathrm{NH}_3\right)_6\right]^{3+} Which of the following complex compounds will exhibit highest paramagnetic behaviour? (At. no. : Ti=22, Cr=24 , Co=27,
(B) Electronic configuration of \mathrm{Cr}^{3+} in \left[\mathrm{Cr}\left(\mathrm{NH}_3\right)_6\right]^{3+}<imgsrc="/api/proxy−image?url=https(C)ElectronicconfigurationofCo3+in<img src="/api/proxy-image?url=https%3A%2F%2Ffirebasestorage.googleapis.com%2Fv0%2Fb%2Fquantrexacademy-app.firebasestorage.app%2Fo%2Fquestions%252Ffigs%252Fpyq%252Fneet%252FJsz2HEX8kAicsJy3EKu0ZS7D4CEO_iDLG62JVV-iEKQ.original.fullsize.png%3Falt%3Dmedia&clean=1&v=wm2" data-qx-orig-src="https://firebasestorage.googleapis.com/v0/b/quantrexacademy-app.firebasestorage.app/o/questions%2Ffigs%2Fpyq%2Fneet%2FJsz2HEX8kAicsJy3EKu0ZS7D4CEO_iDLG62JVV-iEKQ.original.fullsize.png?alt=media" data-qx-storage-src="https://firebasestorage.googleapis.com/v0/b/quantrexacademy-app.firebasestorage.app/o/questions%2Ffigs%2Fpyq%2Fneet%2FJsz2HEX8kAicsJy3EKu0ZS7D4CEO_iDLG62JVV-iEKQ.original.fullsize.png?alt=media"><br> (C) Electronic configuration of \mathrm{Co}^{3+} in\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+} :Which of the following complex compounds will exhibit highest paramagnetic behaviour? (At. no. : Ti=22, Cr=24 , Co=27,
In the presence of strong field ligand \mathrm{NH}_3,pairingofelectronstakesplaceandthus,octahedralcomplex,, pairing of electrons takes place and thus, octahedral complex,\quad\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+} is diamagnetic. \left[\mathrm{Co}\left(\mathrm{NH}}_{3}\right)_6\right]^{3+} \left[ inner orbital or  low spin complex \begin{array}{l} \text{ inner orbital or }\\ \text{ low spin complex } \end{array}\right]\left(6 \mathrm{NH}}_{3} \text{ molecules }\right)<img src="/api/proxy-image?url=https%3A%2F%2Ffirebasestorage.googleapis.com%2Fv0%2Fb%2Fquantrexacademy-app.firebasestorage.app%2Fo%2Fquestions%252Ffigs%252Fpyq%252Fneet%252F5FluQ1pEDh1Nq_kiQOQl__QLG0pvmtQH6VDqi8ZzSi4.original.fullsize.png%3Falt%3Dmedia&clean=1&v=wm2" data-qx-orig-src="https://firebasestorage.googleapis.com/v0/b/quantrexacademy-app.firebasestorage.app/o/questions%2Ffigs%2Fpyq%2Fneet%2F5FluQ1pEDh1Nq_kiQOQl__QLG0pvmtQH6VDqi8ZzSi4.original.fullsize.png?alt=media" data-qx-storage-src="https://firebasestorage.googleapis.com/v0/b/quantrexacademy-app.firebasestorage.app/o/questions%2Ffigs%2Fpyq%2Fneet%2F5FluQ1pEDh1Nq_kiQOQl__QLG0pvmtQH6VDqi8ZzSi4.original.fullsize.png?alt=media"> \\ (D) Electronic configuration of \mathrm{Zn}^{2+} in\left[\mathrm{Zn}\left(\mathrm{NH}}_{3}\right)_6\right]^{2+} :Which of the following complex compounds will exhibit highest paramagnetic behaviour? (At. no. : Ti=22, Cr=24 , Co=27, \\ \therefore\left[\mathrm{Zn}\left(\mathrm{NH}}_{3}\right)_6\right]^{2+} is an outer orbital complex and is diamagnetic.
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