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NEET2010ChemistryCoordination CompoundsActual

Which one of the following complexes is not expected to exhibit isomerism?

Options

  1. A[ Ni ( NH ₃ )₄ ( H ₂ O )₂ ]²⁺
  2. B[ Pt ( NH ₃ )₂ Cl ₂ ]
  3. C[ Ni ( NH ₃ )₂ Cl ₂ ]
  4. D[ Ni ( en )₃ ]²⁺

Correct answer

C. [ Ni ( NH ₃ )₂ Cl ₂ ]

Step-by-step solution

[ Ni ( NH ₃ )₂ Cl ₂ ] has tetrahedral geometry and thus, does not exhibit isomerism due to presence of symmetry elements.

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