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NEET 2005
Exam
NEET
Year
2005
Subject
Chemistry
Chapter
Coordination Compounds

NEET 2005 · Chemistry · Coordination Compounds

Which one of the following is an inner orbital complex as well as...

Which one of the following is an inner orbital complex as well as diamagnetic in behaviour? (Atomic number : Zn=30,Cr=24\mathrm{Zn}=30, \mathrm{Cr}=24, Co\mathrm{Co} =27,Ni=28=27, \mathrm{Ni}=28 )Which one of the following is an inner orbital complex as well as diamagnetic in behaviour? (Atomic number : Zn=30,Which one of the following is an inner orbital complex as well as diamagnetic in behaviour? (Atomic number : Zn=30,

Options

  1. A\left[\mathrm{Zn}\left(\mathrm{NH}_3\right)_6\right]^{2+}
  2. B\left[\mathrm{Cr}\left(\mathrm{NH}_3\right)_6\right]^{3+}
  3. C\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}
  4. D\left[\mathrm{Ni}\left(\mathrm{NH}_3\right)_6\right]^{2+}

Correct answer

C. \left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}

Step-by-step solution

Which one of the following is an inner orbital complex as well as diamagnetic in behaviour? (Atomic number : Zn=30,
d2sp3→d^2 s p^3 \rightarrow inner octahedral complex \ diamagnetic. \left[\mathrm{Zn}\left(\mathrm{NH}}_{3}\right)_6\right]^{2+} \longrightarrow s p^2 d^2 hybridization (outer) and diamagnetic. \left[\mathrm{Cr}\left(\mathrm{NH}_3\right)_6\right]^{3+} \longrightarrowd2sp3d^2 s p³ (inner) and paramagnetic. \left[\mathrm{Ni}\left(\mathrm{NH}_3\right)_6\right]^{3+} \longrightarrowsp3p2s p³ p² (outer) and paramagnetic. Related Theory The main difference between inner and outer orbital complexes is that the hybridization of the atomic orbitals of the central metal atom of inner orbital complex involves inner shell dd orbitals whereas the hybridization of the atomic orbitals of the central metal atom of outer orbital complex involves outermost shell d orbitals.
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