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NEET2004ChemistryCoordination CompoundsActual

CN ⁻ is strong field ligand. This is due to the fact that :

Options

  1. Ait carries negative charge
  2. Bit is a pseudohalide
  3. Cit can accept electrons from metal species
  4. Dit form high spin complexes with metal species

Correct answer

B. it is a pseudohalide

Step-by-step solution

Cyanide ion is strong field ligand because it is a pseudohalide ion. Pseudohalide ions are stronger coordinating ligand & they have the ability to form bond (from the pseudohalide to the metal) and bond (from the metal to pseudohalide). Related Theory A pseudohalide is an anion which has similar properties to a halogen, but not a real halogen. Pseudohalogens are polyatomic analogues of halogens, or also called 'fake' halogens, whose properties resemble that of true halogens.

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