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NEET 2004
Exam
NEET
Year
2004
Subject
Chemistry
Chapter
Coordination Compounds

NEET 2004 · Chemistry · Coordination Compounds

Among [Ni(CO)_4], [Ni(CN)_4]^ 2- [NiCl_4]^ 2- species the...

Among [Ni(CO)4],\left[\mathrm{Ni}(\mathrm{CO})_4\right],\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}[NiCl4]2−\left[\mathrm{NiCl}_4\right]^{2-} species the hybridisation states at the Ni\mathrm{Ni} atom are respectively: [Atomic number of Ni=28\mathrm{Ni}=28 ]Among [Ni(CO)_4], [Ni(CN)_4]^ 2- [NiCl_4]^ 2- species the hybridisation states at the Ni atom are respectively: [Atomic

Options

  1. Asp3,dsp3,dsp2s p^3, d s p^3, d s p^2
  2. Bsp3,dsp2,sp3s p^3, d s p^2, s p^3
  3. Csp3,sp3,dsp2s p^3, s p^3, d s p^2
  4. Ddsp2,sp3,sp3d s p^2, s p^3, s p^3

Correct answer

B. sp3,dsp2,sp3s p^3, d s p^2, s p^3

Step-by-step solution

Among [Ni(CO)_4], [Ni(CN)_4]^ 2- [NiCl_4]^ 2- species the hybridisation states at the Ni atom are respectively: [Atomic Related Theory The hybridization of the atomic orbitals of the central metal atom of inner orbital complex involves inner shell dd orbitals whereas the hybridization of the atomic orbitals of the central metal atom of outer orbital complex involves outermost shell dd.
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