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NEET 2007
Exam
NEET
Year
2007
Subject
Chemistry
Chapter
General Organic Chemistry

NEET 2007 · Chemistry · General Organic Chemistry

Consider the following compounds: (i) C_6 H_5 COCl The correct...

Consider the following compounds:  (i) C6H5COClThecorrectdecreasingorderoftheirreactivitytowardshydrolysisis:\text{ (i) } \mathrm{C}_6 \mathrm{H}_5 \mathrm{COCl} The correct decreasing order of their reactivity towards hydrolysis is:Consider the following compounds: (i) C_6 H_5 COCl The correct decreasing order of their reactivity towards hydrolysis

Options

  1. A(i) >> (ii) >> (iii) >> (iv)
  2. B(iv) >> (ii) >> (i) >> (iii)
  3. C(ii) >> (iv) >> (i) >> (iii)
  4. D(ii) >> (iv) >> (iii) >> (iv)

Correct answer

C. (ii) >> (iv) >> (i) >> (iii)

Step-by-step solution

Electron withdrawing group increases the positive charge and electron releasing group decreases the negative change. The degree of hydrolysis increases as the magnitude of positive charge on carbonyl group increases. Among these NO2\mathrm{NO}_2 \& CHO\mathrm{CHO} are electron withdrawing group from which NO2\mathrm{NO}_2 has more −I-\mathrm{I} effect than-CHO. On the other hand CH3\mathrm{CH}_3 is a electron releasing group. Thus, the order of reactivity towards hydrolysis is Consider the following compounds: (i) C_6 H_5 COCl The correct decreasing order of their reactivity towards hydrolysis
Related Theory The mesomeric effect is negative (−M)(-M) when the substituent is an electron-withdrawing group and the effect is positive (+M)(+M) when the substituent is an electron donating group.
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