Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
NEET 2022
Exam
NEET
Year
2022
Subject
Chemistry
Chapter
p Block Elements (Group 15, 16, 17 & 18)

NEET 2022 · Chemistry · p Block Elements (Group 15, 16, 17 & 18)

Which of the following reactions is a part of the large scale...

Which of the following reactions is a part of the large scale industrial preparation of nitric acid?

Options

  1. ANaNO3+H2SO4Pt500 K,9barNaHSO4+HNO3\mathrm{NaNO}_3+\mathrm{H}_2 \mathrm{SO}_4 \frac{\mathrm{Pt}}{500 \mathrm{~K}, 9 \mathrm{bar}} \mathrm{NaHSO}_4 +\mathrm{HNO}_3
  2. B4NH3+5O2 (from air) Pt500K,9 bar 4NO+6H24 \mathrm{NH}_3+5 \mathrm{O}_2 \text{ (from air) } \frac{\mathrm{Pt}}{500 \mathrm{ K}, 9 \text{ bar }} 4 \mathrm{NO} + 6 \mathrm{H}_2O\mathrm{O}
  3. C4HPO3+2N2O5Pt500K,9 bar 4HNO3+P44 \mathrm{HPO}_3+2 \mathrm{ N}_2 \mathrm{O}_5 \frac{\mathrm{Pt}}{500 \mathrm{ K}, 9 \text{ bar }} 4 \mathrm{HNO}_3 +\mathrm{P}_4O10\mathrm{O}_{10}
  4. DCu(NO3)2+2NO2+2H2O⟶ba500Pt,9bar4HNO3+Cu\mathrm{Cu}\left(\mathrm{NO}_3\right)_2+2 \mathrm{NO}_2+2 \mathrm{H}_2 \mathrm{O} \underset{500 \mathrm{Pt}, 9 \mathrm{bar}}{\stackrel{\mathrm{ba}}{\longrightarrow}} 4 \mathrm{HNO}_3+\mathrm{Cu}

Correct answer

B. 4NH3+5O2 (from air) Pt500K,9 bar 4NO+6H24 \mathrm{NH}_3+5 \mathrm{O}_2 \text{ (from air) } \frac{\mathrm{Pt}}{500 \mathrm{ K}, 9 \text{ bar }} 4 \mathrm{NO} + 6 \mathrm{H}_2O\mathrm{O}

Step-by-step solution

The balanced chemical equation involved in manufacturing of (\mathrm{HNO}_3) by Ostwald's process are shown as: Step 1 Formation of nitric oxide (NO) (4 \mathrm{NH}_3(\mathrm{~g})+5 \mathrm{O}_2(\mathrm{~g}) \xrightarrow[500 \mathrm{~K}, 9 \text{ bar }]{\stackrel{\mathrm{Pt} / \mathrm{Rh} \text{, gases- catalyst }}{ }} 4 \mathrm{NO}(\mathrm{g})+6 \mathrm{H}_2 \mathrm{O}) Step 2 Formation of nitrogen dioxide (\left(\mathrm{NO}_2\right)) (2 \mathrm{NO}(\mathrm{g})+\mathrm{O}_2(\mathrm{g}) \rightarrow 2 \mathrm{NO}_2(\mathrm{~g})) Step 3 Absorption of (\mathrm{NO}_2) (Formation of (\mathrm{HNO}_3) ) (3 \mathrm{NO}_2(\mathrm{~g})+\mathrm{H}_2 \mathrm{O} \rightarrow 2 \mathrm{HNO}_3(I\mathrm{I})+\mathrm{NO}(\mathrm{g}))
Practice p Block Elements (Group 15, 16, 17 & 18) on Quantrex Academy →

More from p Block Elements (Group 15, 16, 17 & 18)

Identify the incorrect statement from the following : NEET 2026Given below are two statements: Statement-I : Heating NaCl with concentrated H _2 SO _4… NEET 2026Given below are two statements: Statement I : Like nitrogen that can form ammonia… NEET 2025Match List - I with List-II List-I List-II A. XeO_3 I. sp^3 d, linear B. XeF_2 II. sp^3… NEET 2025Among Group 16 elements, which one does NOT show -2 oxidation state? NEET 2024Identify the incorrect statement. NEET 2024The products A and B obtained in the following reactions, respectively, are aligned & 3… NEET 2024Given below are two statements: Statement I: The boiling point of hydrides of Group 16… NEET 2024 Full p Block Elements (Group 15, 16, 17 & 18) list All NEET PYQs