NTA Abhyas JEE Main2020ChemistryAlcohols Phenols and EthersPractice
What will be the correct decreasing order of acid strength of the hydroxybenzoic acids? (Symbols and notations carry their usual meanings)
Options
- Ap-Hydroxybenzoic acid > benzoic acid > m-hydroxybenzoic acid > o-hydroxybenzoic acid
- Bo-Hydroxybenzoic acid > m-hydroxybenzoic acid > benzoic acid > p-hydroxybenzoic acid
- Co-Hydroxybenzoic acid > benzoic acid > m-hydroxybenzoic acid > p-hydroxybenzoic acid
- Dm-Hydroxybenzoic acid > benzoic acid > o-hydroxybenzoic acid > p-hydroxybenzoic acid
Correct answer
B. o-Hydroxybenzoic acid > m-hydroxybenzoic acid > benzoic acid > p-hydroxybenzoic acid
Step-by-step solution
In case of hydroxybenzoic acids, they display both kind of effect and there is a decrease in electron density at all positions due to inductive effect of -OH group, but increase in electron density at o- and p-positions due to resonance effect by -OH group. o-hydroxy benzoic acid is strongest among the given acids due to intramolecular hydrogen bonding in its conjugate base