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NTA Abhyas 2020
Exam
NTA Abhyas
Year
2020
Subject
Chemistry
Chapter
p Block Elements (Group 13 & 14)

NTA Abhyas 2020 · Chemistry · p Block Elements (Group 13 & 14)

In the context of the Hall-Heroult process for the extraction of...

In the context of the Hall-Heroult process for the extraction of Al,\text{Al,} which of the following statements is false ?

Options

  1. ACO and CO2{CO}_{2} are produced in this process
  2. BA{l}_{2}{O}_{3}ismixedwithis mixed withCa{F}_{2}whichlowersthemeltingpointofthemixtureandbringsconductivitywhich lowers the melting point of the mixture and brings conductivity
  3. CAl3+Al^{3 +} is reduced at the cathode to form Al
  4. DNa3AlF6N{a}_{3}Al{F}_{6} helps in increasing the melting point of the mixture

Correct answer

D. Na3AlF6N{a}_{3}Al{F}_{6} helps in increasing the melting point of the mixture

Step-by-step solution

Hall heroult process:
In the Hall-Héroult process the following simplified reactions take place at the carbon electrodes:
Cathode: Al3++3e−1→AlAl^{3 +} + 3e^{- 1} \to Al
Anode: O2−+C→CO+2e−O^{2 -} + C \to CO + 2e^{-}

Overall:
A{l}_{2}{O}_{3} + 3C \to 2Al + 3CO<br/>And2Al2O3+3C→4Al+3CO2<br />And 2A{l}_{2}{O}_{3} + 3C \to 4Al + 3C{O}_{2}

In reality, much more CO2C{O}_{2} is formed at the anode than CO:CO:
Cryolite (N{a}_{3}Al{F}_{6})lowersthemeltingpointofthemixtureandmakeitmoreconductiveinnaturesoastocarryoutelectrolysisoftheoreinHall−Heroultprocess.) lowers the melting point of the mixture and make it more conductive in nature so as to carry out electrolysis of the ore in Hall-Heroult process.
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