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NTA Abhyas 2020
Exam
NTA Abhyas
Year
2020
Subject
Chemistry
Chapter
Solid State

NTA Abhyas 2020 · Chemistry · Solid State

A metallic element crystallizes into a lattice containing a...

A metallic element crystallizes into a lattice containing a sequence of hexagonal layers of ABABAB....... What percentage by volume of this lattice is empty space?

Options

  1. A26%
  2. B74%
  3. C50%
  4. D85%

Correct answer

A. 26%

Step-by-step solution

Number of atoms in hcp is 6 per unit cell.

Packing fraction = \dfrac{6 \times \dfrac{4}{3} {\text{\pi r}^{3}}{\text{Base area} \times \text{C}}

Base area = 6 \times \dfrac{\sqrt{3}}{4} \left(\text{4}{\text{r}^{2}\right)<br /><br /> C = 4r(23)<br/><br/>Packingfraction=π32=0.74<br/><br/>Void\text{4r}\sqrt{\left(\dfrac{2}{3}\right)}<br /><br />Packing fraction =\dfrac{\pi}{3}\sqrt{2} =0 . \text{74}<br /><br />Void %= \left(1 - 0 . \text{74}\right) \times100 = \text{26}%
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