JEE Advanced2024ChemistryCoordination CompoundsActual
Among the following options, select the option in which each complex in Set-I shows geometrical isomerism and the two complexes in Set-II are ionization isomers of each other. [en .= H ₂ NCH ₂ CH ₂ NH ₂ ]
Options
- ASet-I: [ Ni ( CO )₄ ] and [ PdCl ₂ ( PPh ₃ )₂ ] Set-II: [ Co ( NH ₃ )₅ Cl ] SO ₄ and [ Co ( NH ₃ )₅ ( SO ₄ ) ]
- BSet-I: [ Co ( en ) ( NH ₃ )₂ Cl 2 ] and [ PdCl ₂ ( PPh ₃ )₂ ] Set-II: [ Co ( NH ₃ )₆ ] [ Cr ( CN )₆ ] and [ Cr
- CSet-I: [ Co ( NH ₃ )₃ ( NO ₂ )₃ ] and [ Co ( en )₂ Cl ₂ ] Set-II: [ Co ( NH ₃ )₅ Cl ] SO ₄ and [ Co ( NH ₃ )₅
- DSet-I: [ Cr ( NH ₃ )₅ Cl ] Cl ₂ and [ Co ( en ) ( NH ₃ )₂ Cl ₂ ] Set-II: [ Cr ( H ₂ O )₆ ] Cl ₃ and [ Cr ( H ₂
Correct answer
C. Set-I: [ Co ( NH ₃ )₃ ( NO ₂ )₃ ] and [ Co ( en )₂ Cl ₂ ] Set-II: [ Co ( NH ₃ )₅ Cl ] SO ₄ and [ Co ( NH ₃ )₅
Step-by-step solution
Set-I: ( [ Co ( NH ₃ )₃ ( NO ₂ )₃ ] ) and ( [ Co (e n)₂ Cl ₂ ] ) Set-II: ( [ Co ( NH ₃ )₅ Cl ] SO ₄ ) and ( [ Co ( NH ₃ )₅ ( SO ₄ ) ] Cl ) Set-I: Set-II: ( [ Co ( NH ₃ )₅ Cl ] SO ₄ ) and ( [ Co ( NH ₃ )₅ SO ₄ ] Cl ) are ionisation isomers.