JEE Advanced 2024Paper 1
- Exam
- JEE Advanced
- Year
- 2024
- Paper
- Paper 1
- Subject
- Chemistry
- Chapter
- Coordination Compounds
JEE Advanced 2024 · Paper 1 · Chemistry · Coordination Compounds
Among the following complexes, the total number of diamagnetic...
Among the following complexes, the total number of diamagnetic species is_____
, and \left[\mathrm{Co}(\mathrm{en})_3\right]^{3+}\mathrm{Mn}=25, \mathrm{Fe}=26, \mathrm{Co}=27\text{ en } \left.=\mathrm{H}_2 \mathrm{NCH}_2 \mathrm{CH}_2 \mathrm{NH}_2\right]
Correct answer
0
Step-by-step solution
configuration in and orbitals will always have unpaired electrons irrespective of SFL and WFL.
configuration will also have unpaired electron irrespective of SFL and WFL.
it can be both paramagnetic or diamagnetic based on field of ligands.
In case of weak field ligand, configuration will be hence it is paramagnetic but in case of
en strong filed ligand, configuration will be hence it will be diamagnetic.
So,
(\left[\mathrm{Mn}\left(\mathrm{NH}_3\right) 6\right]^{3+}) : Paramagnetic
(\left[\mathrm{MnCl}_6\right]^{3-}) : Paramagnetic
(\left[\mathrm{FeF}_6\right]^{3-}) : Paramagnetic
(\left[\mathrm{CoF}_6\right]^{3-}) : Paramagnetic
(\left[\mathrm{Fe}\left(\mathrm{NH}_3\right)_6\right]^{3+}) : Paramagnetic
(\left[\mathrm{Co}(\mathrm{en})_3\right]^{3+}) : Diamagnetic
Only 1 complex is diamagnetic.