JEE Advanced2014ChemistryCoordination CompoundsActual
Match each coordination compound in List-I with an appropriate pair of characteristics from List-II and select the correct answer using the code given below the lists e n = H 2 N C H 2 C H 2 N H 2 ; a t o m i c n u m b e r s : T i = 22 , C r = 24 ; C o = 27 ; P t = 78 List – I List – II A. C r N H 3 4 C l 2 C l P. Paramagnetic and exhibits ionization isomerism B. T i H 2 O 5 C l N O 3 2 Q. Diamagnetic and
Options
- Aa-r;b-p;c-s;d-q;
- Ba-s;b-r;c-p;d-q;
- Ca-q;b-s;c-r;d-p;
- Da-q;b-p;c-s;d-r;
Correct answer
A. a-r;b-p;c-s;d-q;
Step-by-step solution
(P) C r N H 3 4 C l 2 C l → P a r a m a g n e t i c a n d e x h i b i t s c i s - t r a n s i s o m e r i s m (Q) T i H 2 O 5 C l N O 3 2 → P a r a m a g n e t i c a n d e x h i b i t s i o n i z a t i o n i s o m e r i s m (R) P t e n N H 3 C l N O 3 → Diamagnetic and exhibits ionization isomerism (S) C o N H 3 4 N O 3 2 N O 3 → Diamagnetic and exhibits cis - trans isomerism