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JEE Advanced 2014Paper 2
Exam
JEE Advanced
Year
2014
Paper
Paper 2
Subject
Chemistry
Chapter
Coordination Compounds

JEE Advanced 2014 · Paper 2 · Chemistry · Coordination Compounds

Match each coordination compound in List-I with an appropriate pair...

Match each coordination compound in List-I with an appropriate pair of characteristics from List-II and
select the correct answer using the code given below the lists
{en=H2NCH2CH2NH2;atomicnumbers:Ti=22,Cr=24;Co=27;Pt=78}\left\{en = {H}_{2}NC{H}_{2}C{H}_{2}N{H}_{2}; atomicnumbers: {T}_{i} = 22, Cr = 24; Co = 27; Pt = 78\right\}
List – I List – II
A. [Cr(NH3)4Cl2]Cl\left[Cr{\left(N{H}_{3}\right)}_{4}C{l}_{2}\right]Cl P. Paramagnetic and exhibits ionization isomerism
B. [Ti(H2O)5Cl](NO3)2\left[Ti{\left({H}_{2}O\right)}_{5}Cl\right]{\left(N{O}_{3}\right)}_{2} Q. Diamagnetic and exhibits cis - trans isomerism
C. [Pt(en)(NH3)Cl]NO3\left[Pt\left(en\right)\left(N{H}_{3}\right)Cl\right]N{O}_{3} R. Paramagnetic and exhibits cis - trans isomerism
D. [Co(NH3)4(NO3)2]NO3\left[Co{\left(N{H}_{3}\right)}_{4}{\left(N{O}_{3}\right)}_{2}\right]N{O}_{3} S. Diamagnetic and exhibits ionization isomerism

Options

  1. Aa-r;b-p;c-s;d-q;
  2. Ba-s;b-r;c-p;d-q;
  3. Ca-q;b-s;c-r;d-p;
  4. Da-q;b-p;c-s;d-r;

Correct answer

A. a-r;b-p;c-s;d-q;

Step-by-step solution

(P) [Cr(NH3)4Cl2]Cl→Paramagneticandexhibitscis−transisomerism\left[Cr{\left(N{H}_{3}\right)}_{4}C{l}_{2}\right]Cl \to Paramagneticandexhibitscis - transisomerism
(Q) \left[Ti{\left({H}_{2}O\right)}_{5}Cl\right]{\left(N{O}_{3}\right)}_{2} \to Paramagneticandexhibitsionizationisomerism<br/>(R)[Pt(en)(NH3)Cl]NO3→<br />(R) \left[Pt\left(en\right)\left(N{H}_{3}\right)Cl\right]N{O}_{3} \to Diamagnetic and exhibits ionization isomerism
(S) \left[Co{\left(N{H}_{3}\right)}_{4}{\left(N{O}_{3}\right)}_{2}\right]N{O}_{3} \to Diamagnetic and exhibits cis - trans isomerism
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