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JEE Advanced 2011Paper 1
Exam
JEE Advanced
Year
2011
Paper
Paper 1
Subject
Chemistry
Chapter
Coordination Compounds

JEE Advanced 2011 · Paper 1 · Chemistry · Coordination Compounds

Paragraph: When a metal rod M is dipped into an aqueous colourless...

Paragraph: When a metal rod MM is dipped into an aqueous colourless concentrated solution of compound N\mathrm{N}, the solution turns light blue. Addition of aqueous NaCl\mathrm{NaCl} to the blue solution gives a white precipitate O\mathrm{O}. Addition of aqueous NH3\mathrm{NH}_3 dissolves O\mathrm{O} and gives an intense blue solution.Question: The final solution containsParagraph: When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N , the solution

Options

  1. A\left[\mathrm{Pb}\left(\mathrm{NH}_3\right)_4\right]^{2+} and [CoCl4]2−\left[\mathrm{CoCl}_4\right]^{2-}
  2. B[Al(NH3)4]3+\left[\mathrm{Al}\left(\mathrm{NH}_3\right)_4\right]^{3+} and \left[\mathrm{Cu}\left(\mathrm{NH}_3\right)_4\right]^{2+}
  3. C[Ag(NH3)2]+\left[\mathrm{Ag}\left(\mathrm{NH}_3\right)_2\right]^{+}and \left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4\right]^{2+}
  4. D[Ag(NH3)2]+\left[\mathrm{Ag}\left(\mathrm{NH}_3\right)_2\right]^{+}and \left[\mathrm{Ni}\left(\mathrm{NH}_3\right)_6\right]^{2+}

Correct answer

C. [Ag(NH3)2]+\left[\mathrm{Ag}\left(\mathrm{NH}_3\right)_2\right]^{+}and \left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4\right]^{2+}

Step-by-step solution

Since in the beginning, concentrated AgNO3\mathrm{AgNO}_3 solution was taken, some AgNO3\mathrm{AgNO}_3 remain in solution which gives white precipitate of AgCl\mathrm{AgCl} on addition of NaCl\mathrm{NaCl}. The precipitate finally dissolve in ammonia and Cu2+\mathrm{Cu}^{2+} present in solution also forms complex with ammonia as Paragraph: When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N , the solution
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