JEE Advanced 2011Paper 1
- Exam
- JEE Advanced
- Year
- 2011
- Paper
- Paper 1
- Subject
- Chemistry
- Chapter
- Coordination Compounds
JEE Advanced 2011 · Paper 1 · Chemistry · Coordination Compounds
Paragraph: When a metal rod M is dipped into an aqueous colourless...
Paragraph:
When a metal rod is dipped into an aqueous colourless concentrated solution of compound , the solution turns light blue. Addition of aqueous to the blue solution gives a white precipitate . Addition of aqueous dissolves and gives an intense blue solution.Question:
The final solution contains
Options
- A\left[\mathrm{Pb}\left(\mathrm{NH}_3\right)_4\right]^{2+} and
- B and \left[\mathrm{Cu}\left(\mathrm{NH}_3\right)_4\right]^{2+}
- Cand \left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4\right]^{2+}
- Dand \left[\mathrm{Ni}\left(\mathrm{NH}_3\right)_6\right]^{2+}
Correct answer
C. and \left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4\right]^{2+}
Step-by-step solution
Since in the beginning, concentrated solution was taken, some remain in solution which gives white precipitate of on addition of . The precipitate finally dissolve in ammonia and present in solution also forms complex with ammonia as
