JEE Advanced2011ChemistryCoordination CompoundsActual
Paragraph: When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N , the solution turns light blue. Addition of aqueous NaCl to the blue solution gives a white precipitate O . Addition of aqueous NH ₃ dissolves O and gives an intense blue solution. Question: The final solution contains
Options
- A[ Pb ( NH ₃ )₄ ]²⁺ and [ CoCl ₄ ]²⁻
- B[ Al ( NH ₃ )₄ ]³⁺ and [ Cu ( NH ₃ )₄ ]²⁺
- C[ Ag ( NH ₃ )₂ ]⁺ and [ Co ( NH ₃ )₄ ]²⁺
- D[ Ag ( NH ₃ )₂ ]⁺ and [ Ni ( NH ₃ )₆ ]²⁺
Correct answer
C. [ Ag ( NH ₃ )₂ ]⁺ and [ Co ( NH ₃ )₄ ]²⁺
Step-by-step solution
Since in the beginning, concentrated AgNO ₃ solution was taken, some AgNO ₃ remain in solution which gives white precipitate of AgCl on addition of NaCl . The precipitate finally dissolve in ammonia and Cu ²⁺ present in solution also forms complex with ammonia as