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JEE Advanced 2007Paper 1
Exam
JEE Advanced
Year
2007
Paper
Paper 1
Subject
Chemistry
Chapter
Coordination Compounds

JEE Advanced 2007 · Paper 1 · Chemistry · Coordination Compounds

Match the complexes in Column I with their properties listed in...

Match the complexes in Column I with their properties listed in Column II. Indicates your answer by darkening the appropriate bubbles of 4×44 \times 4 matrix given in the ORS. Match the complexes in Column I with their properties listed in Column II. Indicates your answer by darkening the

Options

  1. AA-p, r; B-p, q, s; C-p; D-q, r
  2. BA-p, s; B-p, r, s; C-p, s; D-q, r
  3. CA-p, q, s; B-p, r, s; C-q, s; D-q, s
  4. DA-r, s; B-q; C-p; D-p, q, s

Correct answer

C. A-p, q, s; B-p, r, s; C-q, s; D-q, s

Step-by-step solution

(A) [Co(NH3)4[(H2O)2]Cl2p,q,s\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4\left[\left(\mathrm{H}_2 \mathrm{O}\right)_2\right] \mathrm{Cl}_2 p, q, s\right. Oxidation state Co\mathrm{Co} is +2⇒+2 \Rightarrow Paramagnetic, exhibits geometrical isomerism. (B) [Pt(NH3)4Cl2]p,r,sdsp2\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right] p, r, s \mathrm{dsp}{ }^2-hybridisation Pt2+\mathrm{Pt}^{2+}, diamagnetic square planar, geometrical isomerism (C) q,sq, s (D) q,sq, s
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