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JEE Main 20264 AprilMorning Shift
Exam
JEE Main
Year
2026
Date
4 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Alcohols Phenols and Ethers

JEE Main 2026 · 4 April · Morning Shift · Chemistry · Alcohols Phenols and Ethers

Amongst the following, the total number of compounds soluble in...

Amongst the following, the total number of compounds soluble in aqueous NaOHNaOH at room temperature is:
Amongst the following, the total number of compounds soluble in aqueous NaOH at room temperature is:

Options

  1. A55
  2. B44
  3. C66
  4. D33

Correct answer

A. 55

Step-by-step solution

To determine which compounds are soluble in aqueous NaOHNaOH, we need to identify the compounds that are sufficiently acidic to react with NaOHNaOH (a strong base) to form water-soluble sodium salts. Generally, carboxylic acids and phenols are acidic enough to dissolve in aqueous NaOHNaOH, whereas alcohols, aldehydes, amines, and hydrocarbons are not.

Let us analyze each compound:
(I) Benzaldehyde: It is an aldehyde. It does not have an acidic proton and is insoluble in aqueous NaOHNaOH.
(II) 1-Naphthol: It is a phenol derivative. Phenols are acidic and react with NaOHNaOH to form soluble phenoxide salts. (Soluble)
(III) 4-(Dimethylamino)phenol: It contains a phenolic −OH-OH group. Despite the basic amino group, the acidic phenol group will react with NaOHNaOH to form a soluble salt. (Soluble)
(IV) p-Cresol: It is a phenol derivative. It reacts with NaOHNaOH to form a soluble sodium salt. (Soluble)
(V) Benzoic acid: It is a carboxylic acid, which is highly acidic and readily dissolves in aqueous NaOHNaOH. (Soluble)
(VI) N,N-Dimethylcyclohexanamine: It is an aliphatic amine. It is basic in nature and insoluble in aqueous NaOHNaOH.
(VII) 1-Naphthoic acid: It is a carboxylic acid and will dissolve in aqueous NaOHNaOH. (Soluble)
(VIII) 1,4-Di-tert-butylbenzene: It is a hydrocarbon. It is neutral and insoluble in aqueous NaOHNaOH.
(IX) 1-Naphthalenemethanol: It is an alcohol (benzyl-type). Alcohols are generally not acidic enough to react with aqueous NaOHNaOH. (Insoluble)

The compounds soluble in aqueous NaOHNaOH are (II), (III), (IV), (V), and (VII).
Total number of soluble compounds = 55.

Answer: 55
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