JEE Main 20264 AprilMorning Shift
- Exam
- JEE Main
- Year
- 2026
- Date
- 4 April
- Shift
- Morning Shift
- Subject
- Chemistry
- Chapter
- Alcohols Phenols and Ethers
JEE Main 2026 · 4 April · Morning Shift · Chemistry · Alcohols Phenols and Ethers
Identify the colour of compound 'X' in the sequence of the reaction.
Identify the colour of compound in the sequence of the reaction.

Options
- AViolet
- BGreen
- CRed
- DColourless
Correct answer
D. Colourless
Step-by-step solution
The given reaction sequence represents the synthesis and acid-base behaviour of phenolphthalein.
When phenol reacts with phthalic anhydride in the presence of concentrated , phenolphthalein is formed. In acidic or neutral medium, phenolphthalein exists in a lactone form which is colourless.
Upon addition of a moderate amount of alkali (NaOH), the lactone ring opens and a proton is removed, forming a dianion with an extended conjugated quinonoid structure. This extended conjugation is responsible for the characteristic pink colour of phenolphthalein in basic medium.
When excess NaOH is added (strongly alkaline medium), a hydroxide ion attacks the central hybridized carbon atom of the quinonoid structure. This converts the central carbon to an hybridized state, forming a carbinol structure (compound X).
Because the central carbon is now hybridized, the extended conjugation is broken. As a result, the compound loses its colour and becomes colourless.
Therefore, compound X is colourless.
Answer: Colourless
When phenol reacts with phthalic anhydride in the presence of concentrated , phenolphthalein is formed. In acidic or neutral medium, phenolphthalein exists in a lactone form which is colourless.
Upon addition of a moderate amount of alkali (NaOH), the lactone ring opens and a proton is removed, forming a dianion with an extended conjugated quinonoid structure. This extended conjugation is responsible for the characteristic pink colour of phenolphthalein in basic medium.
When excess NaOH is added (strongly alkaline medium), a hydroxide ion attacks the central hybridized carbon atom of the quinonoid structure. This converts the central carbon to an hybridized state, forming a carbinol structure (compound X).
Because the central carbon is now hybridized, the extended conjugation is broken. As a result, the compound loses its colour and becomes colourless.
Therefore, compound X is colourless.
Answer: Colourless