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JEE Main 20264 AprilMorning Shift
Exam
JEE Main
Year
2026
Date
4 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Alcohols Phenols and Ethers

JEE Main 2026 · 4 April · Morning Shift · Chemistry · Alcohols Phenols and Ethers

Identify the colour of compound 'X' in the sequence of the reaction.

Identify the colour of compound ′X′'X' in the sequence of the reaction.
Identify the colour of compound 'X' in the sequence of the reaction.

Options

  1. AViolet
  2. BGreen
  3. CRed
  4. DColourless

Correct answer

D. Colourless

Step-by-step solution

The given reaction sequence represents the synthesis and acid-base behaviour of phenolphthalein.

When phenol reacts with phthalic anhydride in the presence of concentrated H2SO4H_2SO_4, phenolphthalein is formed. In acidic or neutral medium, phenolphthalein exists in a lactone form which is colourless.

Upon addition of a moderate amount of alkali (NaOH), the lactone ring opens and a proton is removed, forming a dianion with an extended conjugated quinonoid structure. This extended conjugation is responsible for the characteristic pink colour of phenolphthalein in basic medium.

When excess NaOH is added (strongly alkaline medium), a hydroxide ion attacks the central sp2sp^2 hybridized carbon atom of the quinonoid structure. This converts the central carbon to an sp3sp^3 hybridized state, forming a carbinol structure (compound X).

Because the central carbon is now sp3sp^3 hybridized, the extended conjugation is broken. As a result, the compound loses its colour and becomes colourless.

Therefore, compound X is colourless.

Answer: Colourless
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