Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Main 20266 AprilEvening Shift
Exam
JEE Main
Year
2026
Date
6 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Amines

JEE Main 2026 · 6 April · Evening Shift · Chemistry · Amines

Consider the following organic reaction sequence. Choose the final...

Consider the following organic reaction sequence. Choose the final product (X)(X) from the following (consider the major product in all intermediate reactions)
Consider the following organic reaction sequence. Choose the final product (X) from the following (consider the major

Options

  1. ABenzene
  2. BPhenol
  3. CPropanol
  4. DChlorobenzene

Correct answer

A. Benzene

Step-by-step solution

The starting material is propanoic acid (CH3CH2COOHCH_3CH_2COOH).

In step (i), propanoic acid reacts with NH3NH_3 upon heating to form propanamide.
CH3CH2COOH→NH3,ΔCH3CH2CONH2CH_3CH_2COOH \xrightarrow{NH_3, \Delta} CH_3CH_2CONH_2

In step (ii), propanamide undergoes Hoffmann bromamide degradation with NaOHNaOH and Br2Br_2 to form ethylamine.
CH3CH2CONH2→NaOH,Br2CH3CH2NH2CH_3CH_2CONH_2 \xrightarrow{NaOH, Br_2} CH_3CH_2NH_2

In step (iii), ethylamine reacts with nitrous acid (HNO2HNO_2) to form an unstable diazonium salt, which hydrolyzes to give ethanol.
CH3CH2NH2→HNO2,H2OCH3CH2OHCH_3CH_2NH_2 \xrightarrow{HNO_2, H_2O} CH_3CH_2OH

In step (iv), ethanol reacts with benzenediazonium chloride (C6H5N2ClC_6H_5N_2Cl). Ethanol reduces the diazonium salt to benzene, while getting oxidized to ethanal.
CH3CH2OH+C6H5N2Cl→C6H6+CH3CHO+N2+HClCH_3CH_2OH + C_6H_5N_2Cl \rightarrow C_6H_6 + CH_3CHO + N_2 + HCl

The final major product (X) is benzene.

Answer: Benzene
Practice Amines on Quantrex Academy →

More from Amines

Match the major products obtained in the reactions given in List-I with the corresponding… JEE Advanced 2026In the following reaction sequence, P , Q , S and T are the major products. The correct… JEE Advanced 2026Passage: Consider the following reaction sequence in which J , K , L and M are the major… JEE Advanced 2026Which statements are True? A. In Hoffmann bromamide degradation, 4 moles of NaOH and 2… JEE Main 2026The number of compounds from the following which can undergo reaction with Br _2 /KOH… JEE Main 2026Consider the following sequence of reactions. The percentage of nitrogen in the yellow… JEE Main 2026Given below are two statements : Statement I: Heating benzamide with bromine in an… JEE Main 2026Identify the incorrect statements. Choose the correct answer from the options given below: JEE Main 2026 Full Amines list All JEE Main PYQs