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JEE Amines PYQs with Solutions

495 previous year questions from Amines (JEE Main & Advanced Chemistry) with answers and solutions. Numbered list, year tags, and one-tap solutions — built for serious JEE / NEET practice.

495 questionsChemistry2006–2026Answers + solutions

About Amines PYQs

Amines has 495 previous year questions in the Quantrex Academy JEE Main & Advanced Chemistry bank. The 220 questions in this list come from JEE Main (183) and JEE Advanced (37), spanning 2006 to 2026. Each question opens on its own page with the options, the correct answer and the worked solution where available.

Questions by year (this list)

  • 2026: 32
  • 2025: 22
  • 2024: 23
  • 2023: 23
  • 2022: 24
  • 2021: 41
  • 2020: 15
  • 2019: 16
  • 2018: 2
  • 2017: 2
  • 2016: 2
  • 2015: 2

Amines questions with solutions

1

Match the major products obtained in the reactions given in List-I with the corresponding structures in List-II and choose the correct option. List-I List-II (P) (1) (Q) (2) (R)

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2

In the following reaction sequence, P , Q , S and T are the major products. The correct statement(s) about P , Q , S and T is(are)

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3

Passage: Consider the following reaction sequence in which J , K , L and M are the major products. Given: Atomic mass (in amu): H : 1 , C : 12 , N : 14 , O : 16 , S : 32 , Br : 80

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4

Which statements are True? A. In Hoffmann bromamide degradation, 4 moles of NaOH and 2 moles of Br _2 are consumed per mole of an amide B. Hoffmann bromamide reaction is not given

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5

Consider the following organic reaction sequence. Choose the final product (X) from the following (consider the major product in all intermediate reactions)

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6

The number of compounds from the following which can undergo reaction with Br _2 /KOH (alcoholic) to give respective products and these respective products can also be obtained

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7

Consider the following sequence of reactions. The percentage of nitrogen in the yellow product (X) formed is _______%. (Nearest Integer) (Given Molar mass in g mol ^ -1 H:1, C:12

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8

Given below are two statements : Statement I: Heating benzamide with bromine in an ethanolic solution of sodium hydroxide will give benzylamine. Statement II: Nitration of aniline

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9

Identify the incorrect statements. Choose the correct answer from the options given below:

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10

The strongest conjugate acid will result from:

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11

Product C of the following reaction sequence will be

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12

Consider the following reactions sequence When the product (P) is subjected to Carius analysis using AgNO_3 , 1.0 g of the product (P) will produce _______ g of the precipitate of

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13

Match List - I with List - II. List - I Mixture of Compounds List - II Reagent used to distinguish A. Diethyl amine + Ethyl amine I. Bromine water B. Acetaldehyde + Acetone II.

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14

Consider the three aromatic molecules (P, Q and R) whose structures have been given below : The correct order regarding the reactivity of these compounds with Ph-N≡ NCl^ (-) _ (+)

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15

A student performed analysis of aliphatic organic compound ' X ' which on analysis gave C=61.01 \% , H=15.25 \%, ~N=23.74 \% . This compound, on treatment with HNO_ 2 / H_ 2 O

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16

Total number of alkali insoluble solid sulphonamides obtained by reaction of given amines with Hinsberg's reagent is \_\_\_\_ . Aniline, N-Methylaniline, Methanamine, N

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17

Consider the following reactions giving major product. Identify the correct reaction.

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18

Given below are two statements: Statement I : Griss-Ilosvay test is used for the detection of nitrite ion, which involves the use of sulphanilic acid and α -naphthylamine reagent.

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19

Given below are two statements: Statement I : The dipole moment of R-CN is greater than R-NC and R-NC can undergo hydrolysis under acidic medium to produce . Statement II : R-CN

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20

A student has planned to prepare acetanilide from aniline using acetic anhydride. The student has started from 9.3 g of aniline. However, the student has managed to obtain 11 g of

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21

The correct stability order of the following diazonium salts is

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22

A student has been given a compound " x " of molecular formula- C_ 6 H_ 7 ~N . ' x ' is sparingly soluble in water. However, on addition of dilute mineral acid, ' x ' becomes

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23

Given below are two statements: Statement I: can be synthesized from using simpler reagents in the order i) Acidic KMnO_ 4 , ii) Ammonia, iii) Bromine and alkali Statement II: can

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24

Consider the following sequence of reactions. Assuming that the reaction proceeds to completion, then 137 mg of 4 -nitrotoluene will produce \_\_\_\_ mg of B . (Given molar mass

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25

Compound ' P ' undergoes the following sequence of reactions : ' P^ is :

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26

The final product [B] is :

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27

The mass of benzanilide obtained from the benzoylation reaction of 5.8 g of aniline, if yield of product is 82 \% , is \_\_\_\_ g (nearest integer). (Given molar mass in g mol^ -1

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28

' A ' is a neutral organic compound ( M. F: C_ 8 H_ 9 ON ). On treatment with aqueous Br_ 2 / HO^ (-) , ' A ' forms a compound ' B ' which is soluble in dilute acid. ' B ' on

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29

Consider the above sequence of reactions. The number of bromine atom(s) in the final product (P) will be :

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30

A hydrocarbon ' P^ (C_ 4 H_ 8 ) on reaction with HCl gives an optically active compound ' Q ' (C_ 4 H_ 9 Cl) which on reaction with one mole of ammonia gives compound ' R^ (C_ 4

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31

An organic compound (P) on treatment with aqueous ammonia under hot condition forms compound (Q) which on heating with Br_ 2 and KOH forms compound (R) having molecular formula C_

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32

Consider the following reaction sequence The percentage of nitrogen in product ' T ' formed is \_\_\_\_ %. (Nearest integer) (Given molar mass in g mol^ -1 H: 1, C: 12, ~N: 14, O

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33

The major products obtained from the reactions in List-II are the reactants for the named reactions mentioned in List-I. Match each entry in List-I with the appropriate entry in

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34

Match the compounds in List-I with the appropriate observations in List-II and choose the correct option. LIST - I LIST - II (P) (1) Reaction with phenyl diazonium salt gives #ff0

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35

For the reaction sequence given below, the correct statement(s) is(are)

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36

A [ (ii) H_3 O^ + ] (i) NaOH B [ (ii) H_2 SO_4, Δ] (i) EtOH C ' A ' shows positive Lassaign's test for N and its molar mass is 121. ' B ' gives effervescence with aq. NaHCO_3 .

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37

The descending order of basicity of following amines is: Choose the correct answer from the options given below :

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38

Which of the following amine (s) show (s) positive carbylamines test? (A) (B) (CH_3)_2 NH (C) CH_3 NH_2 (D) (CH_3)_3 ~N (E)

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39

The correct order of basicity for the following molecules is:

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40

The major product (A) formed in the following reaction sequence is

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41

The sequence from the following that would result in giving predominantly 3,4,5 -Tribromoaniline is :

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42

Identify [A],[B] , and [C] , respectively in the following reaction sequence :

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43

In the following reactions, which one is NOT correct?

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44

When a concentrated solution of sulphanilic acid and 1-naphthylamine is treated with nitrous acid ( 273 K) and acidified with acetic acid, the mass ( g) of 0.1 mole of product

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45

The correct order of basic nature on aqueous solution for the bases \( NH _ 3 , H _ 2 ~N-NH _ 2 , CH _ 3 CH _ 2 NH _ 2 \), \( (CH _ 3 CH _ 2 )_2 NH \) and \( (CH _ 3 CH _ 2 )_3 ~N

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46

Given below are some nitrogen containing compounds Each of them is treated with HCl separately. 1.0 g of the most basic compound will consume _______ mg of HCl. (Given molar mass

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47

Identify correct statements : (A) Primary amines do not give diazonium salts when treated with NaNO_2 in acidic condition. (B) Aliphatic and aromatic primary amines on heating

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48

For reaction The correct order of set of reagents for the above conversion is :

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49

Consider the following sequence of reactions. Total number of sp^3 hybridised carbon atoms in the major product C formed is________

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50

Which among the following react with Hinsberg's reagent? Choose the correct answer from the options given below:

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51

Consider the following sequence of reactions to produce major product (A) Molar mass of product (A) is g mol^ -1 . (Given molar mass in g mol^ -1 of C: 12, H: 1, O: 16, Br: 80

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52

Match the Compounds (List - I) with the appropriate Catalyst/Reagents (List - II) for their reduction into corresponding amines. Choose the correct answer from the options given

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53

The products formed in the following reaction sequence are :

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54

Consider the following sequence of reactions : Molar mass of the product formed (A) is _______ g mol^ -1 .

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55

List-I contains various reaction sequences and List-II contains different phenolic compounds. Match each entry in List-I with the appropriate entry in List-II and choose the

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56

Major product of the following reaction is

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57

Match List - I with List - II. Choose the correct answer from the options given below :

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58

Given below are two statements : Statement (I) : All the following compounds react with p-toluenesulfonyl chloride. \(C_6 H_5 NH_2 (C_6 H_5)_2 NH (C_6 H_5)_3 ~N\) Statement (II)

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59

If \(279 ~g\) of aniline is reacted with one equivalent of benzenediazonium chloride, the maximum amount of aniline yellow formed will be _______ g. (nearest integer) (consider

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60

Number of amine compounds from the following giving solids which are soluble in \(NaOH\) upon reaction with Hinsberg's reagent is _______

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61

Identify the product (A) in the following reaction.

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62

The ratio of number of oxygen atoms to bromine atoms in the product \(Q\) is ______ \(× 10^ -1 \).

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63

\(9.3 ~g\) of pure aniline upon diazotisation followed by coupling with phenol gives an orange dye. The mass of orange dye produced (assume 100\% yield/conversion) is _______ g.

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64

\( X g \) of ethanamine was subjected to reaction with \( NaNO _ 2 / HCl \) followed by hydrolysis to liberate \( N _ 2 \) and \( HCl \). The \( HCl \) generated was completely

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65

Find out the major product formed from the following reaction. \([Me:-CH_3]\)

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66

Phthalimide is made to undergo following sequence of reactions. Total number of \(π\) bonds present in product 'P' is/are ______

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67

From \(6.55 ~g\) of aniline, the maximum amount of acetanilide that can be prepared will be ______ \(× 10^ -1 ~g\).

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68

\(X g\) of ethylamine is subjected to reaction with \(NaNO_2 / HCl\) followed by water; evolved dinitrogen gas which occupied \(2.24 ~L\) volume at STP. \(X\) is \( \) \(× 10^ -1

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69

Number of compounds which give reaction with Hinsberg's reagent is _________.

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70

Given below are two statements: Statement (I) : The NH _ 2 group in Aniline is ortho and para directing and a powerful activating group. Statement (II) : Aniline does not undergo

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71

Given below are two statements : Statement I: Aniline reacts with con. H _ 2 SO _ 4 followed by heating at 453 - 473K gives p-aminobenzene sulphonic acid, which gives blood red

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72

A compound (x) with molar mass 108g mol ^ - 1 undergoes acetylation to give product with molar mass 192g mol ^ - 1 . The number of amino groups in the compound (x) is ________.

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73

The products A and B formed in the following reaction scheme are respectively

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74

Following is a confirmatory test for aromatic primary amines. Identify reagent (A) and (B)

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75

The final product A , formed in the following multistep reaction sequence is:

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76

Which of the following reaction is correct?

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77

The product A formed in the following reaction is:

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78

The total number of sp ^ 2 hybridised carbon atoms in the major product P (a non-heterocyclic compound) of the following reaction is

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79

Consider the following sequence of reactions The product ‘ B ’ is

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80

In the above conversion the correct sequence of reagents to be added is

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81

Compound A from the following reaction sequence is :

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82

Compoun ' B ' is

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83

Isomeric amines with molecular formula C _ 8 H _ 11 N give the following tests Isomer (P) ⇒ Can be prepared by Gabriel phthalimide synthesis Isomer (Q) ⇒ Reacts with

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84

The product ( P ) formed from the following multistep reaction is:

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85

Match List I with List II : s reacted with reagents in List I to form products in List II products in List II. List I (Reagent) List II (Product) A. I. B. HBF _ 4, Δ II. C. Cu

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86

Number of isomeric aromatic amines with molecular formula C _ 8 H _ 11 N , which can be synthesized by Gabriel Phthalimide synthesis is _____.

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87

The major products A and B from the following reactions are :

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88

The major product formed in the following reaction is

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89

Compound P is neutral, Q gives effervescence with NaHCO _ 3 while R reacts with Hinsberg’s reagent to give solid soluble in NaOH . Compound P is

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90

In the following reaction, ‘ A ’ is

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91

An organic compound [ A ] ( C _ 4 H _ 11 N) , shows optical activity and gives N _ 2 gas on treatment with HNO _ 2 . The compound [ A ] reacts with PhSO _ 2 Cl producing a

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92

How many of the transformation given below would result in aromatic amines?

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93

Benzyl isocyanide can be obtained by: (A) (B) (C) (D) Choose the correct answer from the options given below:

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94

Reaction of propanamide with Br _ 2 / KOH (aq) produces:

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95

The major product ' P ' for the following sequence of reactions is:

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96

Match List I with List II List I (Amines) List II (pKb) A. Aniline I. 3 . 25 B. Ethanamine II. 3 . 00 C. N-Ethylethanamine III. 9 . 38 D. N, N-Diethylethanamine IV. 3 . 29 Choose

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97

The correct order in aqueous medium of basic strength in case of methyl substituted amines is:

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98

Identify the product formed ( A and E )

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99

Given below are two statements : Statement I : Pure Aniline and other arylamines are usually colourless. Statement II : Arylamines get coloured on storage due to atmospheric

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100

Choose the correct colour of the product for the following reaction.

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101

Considering the following reaction sequence, the correct option(s) is(are)

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102

Match the compounds in LIST- I with the observations in LIST- II , and choose the correct option. LIST- I LIST- II (I) Aniline (P) Sodium fusion extract of the compound on boiling

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103

The Hinsberg reagent is

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104

Which among the following is the strongest Bronsted base?

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105

Consider the above reaction, the compound ' A ' is

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106

Which among the following represent reagent ' A '?

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107

Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R Assertion A : Aniline on nitration yields ortho, meta & para nitro

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108

An organic compound ' A ' contains nitrogen and chlorine. It dissolves readily in water to give a solution that turns litmus red. Titration of compound ' A ' with

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109

Match List-I with List-II List-I List-II A Benzenesulphonyl chloride I Test for primary amines B Hoffmann bromamide reaction II Anti Saytzeff C Carbylamine reaction III Hinsberg

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110

Hydrolysis of which compound will give carbolic acid?

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111

The correct sequential order of the reagents for the given reaction is

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112

An organic compound 'A ' on reaction with NH _ 3 followed by heating gives compound B . Which on further strong heating gives compound C ( C _ 8 H _ 5 NO _ 2 ) . Compound

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113

Consider the above reaction, the product A and product B respectively are

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114

With respect to the following reaction, consider the given statements: (A) o -Nitroaniline and p -nitroaniline are the predominant products. (B) p -Nitroaniline and m

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115

Identify the major product formed in the following sequence of reactions :

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116

A primary aliphatic amine on reaction with nitrous acid in cold (273K) and there after raising temperature of reaction mixture to room temperature (298K) , gives a/an

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117

Given below are two statements : Statement - I : In Hofmann degradation reaction, the migration of only an alkyl group takes place from carbonyl carbon of the amide to the

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118

Which statement is NOT correct for p-toluenesulphonyl chloride?

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119

Identify ' Z ' among the following

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120

Among the following structures, which will show the most stable enamine formation? (Where Me is - CH _ 3 )

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