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Amines — JEE Main & Advanced Chemistry PYQs

495 previous year questions from Amines with answers and solutions. Numbered list, year tags, and one-tap solutions — built for serious JEE / NEET practice.

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1

Match the major products obtained in the reactions given in List-I with the corresponding structures in List-II and choose the correct option. List-I List-II (P) (1) (Q) (2) (R) (3

JEE Advanced 2026 Solution View → 2

In the following reaction sequence, P , Q , S and T are the major products. The correct statement(s) about P , Q , S and T is(are)

JEE Advanced 2026 Solution View → 3

Passage: Consider the following reaction sequence in which J , K , L and M are the major products. Given: Atomic mass (in amu): H : 1 , C : 12 , N : 14 , O : 16 , S : 32 , Br : 80

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Which statements are True? A. In Hoffmann bromamide degradation, 4 moles of NaOH and 2 moles of Br₂ are consumed per mole of an amide B. Hoffmann bromamide reaction is not given by

JEE Main 2026 Solution View → 5

Consider the following organic reaction sequence. Choose the final product (X) from the following (consider the major product in all intermediate reactions)

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The number of compounds from the following which can undergo reaction with Br ₂ /KOH (alcoholic) to give respective products and these respective products can also be obtained sepa

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Consider the following sequence of reactions. The percentage of nitrogen in the yellow product (X) formed is _______%. (Nearest Integer) (Given Molar mass in g mol ⁻¹ H:1, C:12, N:

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Given below are two statements : Statement I: Heating benzamide with bromine in an ethanolic solution of sodium hydroxide will give benzylamine. Statement II: Nitration of aniline

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Identify the incorrect statements. Choose the correct answer from the options given below:

JEE Main 2026 Solution View → 10

The strongest conjugate acid will result from:

JEE Main 2026 Solution View → 11

Product C of the following reaction sequence will be

JEE Main 2026 Solution View → 12

Consider the following reactions sequence When the product (P) is subjected to Carius analysis using AgNO₃ , 1.0 g of the product (P) will produce _______ g of the precipitate of A

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Match List - I with List - II. List - I Mixture of Compounds List - II Reagent used to distinguish A. Diethyl amine + Ethyl amine I. Bromine water B. Acetaldehyde + Acetone II. CHC

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Consider the three aromatic molecules (P, Q and R) whose structures have been given below : The correct order regarding the reactivity of these compounds with Ph-N NCl^ (-) _ (+) u

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A student performed analysis of aliphatic organic compound ' X ' which on analysis gave C=61.01 % , H =15.25 %, ~N =23.74 % . This compound, on treatment with HNO ₂ / H ₂ O produce

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Total number of alkali insoluble solid sulphonamides obtained by reaction of given amines with Hinsberg's reagent is _ _ _ _ . Aniline, N-Methylaniline, Methanamine, N, N-Dimethylm

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Consider the following reactions giving major product. Identify the correct reaction.

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Given below are two statements: Statement I : Griss-Ilosvay test is used for the detection of nitrite ion, which involves the use of sulphanilic acid and -naphthylamine reagent. St

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Given below are two statements: Statement I : The dipole moment of R-CN is greater than R-NC and R-NC can undergo hydrolysis under acidic medium to produce . Statement II : R-CN hy

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A student has planned to prepare acetanilide from aniline using acetic anhydride. The student has started from 9.3 g of aniline. However, the student has managed to obtain 11 g of

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The correct stability order of the following diazonium salts is

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A student has been given a compound " x " of molecular formula- C ₆ H ₇ ~N . ' x ' is sparingly soluble in water. However, on addition of dilute mineral acid, ' x ' becomes soluble

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Given below are two statements: Statement I: can be synthesized from using simpler reagents in the order i) Acidic KMnO ₄ , ii) Ammonia, iii) Bromine and alkali Statement II: can b

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Consider the following sequence of reactions. Assuming that the reaction proceeds to completion, then 137 mg of 4 -nitrotoluene will produce _ _ _ _ mg of B . (Given molar mass in

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Compound ' P ' undergoes the following sequence of reactions : ' P ^ is :

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The final product [ B ] is :

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The mass of benzanilide obtained from the benzoylation reaction of 5.8 g of aniline, if yield of product is 82 % , is _ _ _ _ g (nearest integer). (Given molar mass in g mol ⁻¹ H :

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' A ' is a neutral organic compound ( M . F : C ₈ H ₉ ON ). On treatment with aqueous Br ₂ / HO ^ (-) , ' A ' forms a compound ' B ' which is soluble in dilute acid. ' B ' on treat

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Consider the above sequence of reactions. The number of bromine atom(s) in the final product (P) will be :

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A hydrocarbon ' P ^ ( C ₄ H ₈ ) on reaction with HCl gives an optically active compound ' Q ' ( C ₄ H ₉ Cl ) which on reaction with one mole of ammonia gives compound ' R ^ ( C ₄ H

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An organic compound ( P ) on treatment with aqueous ammonia under hot condition forms compound (Q) which on heating with Br ₂ and KOH forms compound (R) having molecular formula C

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Consider the following reaction sequence The percentage of nitrogen in product ' T ' formed is _ _ _ _ %. (Nearest integer) (Given molar mass in g mol ⁻¹ H : 1, C : 12, ~N : 14, O

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The major products obtained from the reactions in List-II are the reactants for the named reactions mentioned in List-I. Match each entry in List-I with the appropriate entry in Li

JEE Advanced 2025 Solution View → 34

Match the compounds in List-I with the appropriate observations in List-II and choose the correct option. List-I List-II (P) (1) Reaction with phenyl diazonium salt gives #ff0 dye.

JEE Advanced 2025 Solution View → 35

For the reaction sequence given below, the correct statement(s) is(are)

JEE Advanced 2025 Solution View → 36

A [ (ii) H ₃ O ⁺] (i) NaOH B [ (ii) H ₂ SO ₄, ] (i) EtOH C ' A ' shows positive Lassaign's test for N and its molar mass is 121. ' B ' gives effervescence with aq. NaHCO ₃ . 'C' gi

JEE Main 2025 Solution View → 37

The descending order of basicity of following amines is: Choose the correct answer from the options given below :

JEE Main 2025 Solution View → 38

Which of the following amine (s) show (s) positive carbylamines test? (A) (B) ( CH ₃ )₂ NH (C) CH ₃ NH ₂ (D) ( CH ₃ )₃ ~N (E)

JEE Main 2025 Solution View → 39

The correct order of basicity for the following molecules is:

JEE Main 2025 Solution View → 40

The major product (A) formed in the following reaction sequence is

JEE Main 2025 Solution View → 41

The sequence from the following that would result in giving predominantly 3,4,5 -Tribromoaniline is :

JEE Main 2025 Solution View → 42

Identify [ A ],[ B ] , and [ C ] , respectively in the following reaction sequence :

JEE Main 2025 Solution View → 43

In the following reactions, which one is NOT correct?

JEE Main 2025 Solution View → 44

When a concentrated solution of sulphanilic acid and 1-naphthylamine is treated with nitrous acid ( 273 K) and acidified with acetic acid, the mass ( g) of 0.1 mole of product form

JEE Main 2025 Solution View → 45

The correct order of basic nature on aqueous solution for the bases ( NH ₃, H ₂ ~N - NH ₂, CH ₃ CH ₂ NH ₂ ), ( ( CH ₃ CH ₂ )₂ NH ) and ( ( CH ₃ CH ₂ )₃ ~N ) is :

JEE Main 2025 Solution View → 46

Given below are some nitrogen containing compounds Each of them is treated with HCl separately. 1.0 g of the most basic compound will consume _______ mg of HCl. (Given molar mass i

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Identify correct statements : (A) Primary amines do not give diazonium salts when treated with NaNO ₂ in acidic condition. (B) Aliphatic and aromatic primary amines on heating with

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For reaction The correct order of set of reagents for the above conversion is :

JEE Main 2025 Solution View → 49

Consider the following sequence of reactions. Total number of sp ^3 hybridised carbon atoms in the major product C formed is________

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Which among the following react with Hinsberg's reagent? Choose the correct answer from the options given below:

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Consider the following sequence of reactions to produce major product (A) Molar mass of product ( A ) is g mol ⁻¹ . (Given molar mass in g mol ⁻¹ of C : 12, H : 1, O : 16, Br : 80,

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Match the Compounds (List - I) with the appropriate Catalyst/Reagents (List - II) for their reduction into corresponding amines. Choose the correct answer from the options given be

JEE Main 2025 Solution View → 53

The products formed in the following reaction sequence are :

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Consider the following sequence of reactions : Molar mass of the product formed (A) is _______ g mol ⁻¹ .

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List-I contains various reaction sequences and List-II contains different phenolic compounds. Match each entry in List-I with the appropriate entry in List-II and choose the correc

JEE Advanced 2024 Solution View → 56

Major product of the following reaction is

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Match List - I with List - II. Choose the correct answer from the options given below :

JEE Main 2024 Solution View → 58

Given below are two statements : Statement (I) : All the following compounds react with p-toluenesulfonyl chloride. ( C ₆ H ₅ NH ₂ ( C ₆ H ₅ )₂ NH ( C ₆ H ₅ )₃ ~N ) Statement (II)

JEE Main 2024 Solution View → 59

If (279 ~g ) of aniline is reacted with one equivalent of benzenediazonium chloride, the maximum amount of aniline yellow formed will be _______ g. (nearest integer) (consider comp

JEE Main 2024 Solution View → 60

Number of amine compounds from the following giving solids which are soluble in ( NaOH ) upon reaction with Hinsberg's reagent is _______

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Identify the product (A) in the following reaction.

JEE Main 2024 Solution View → 62

The ratio of number of oxygen atoms to bromine atoms in the product ( Q ) is ______ ( 10⁻¹ ).

JEE Main 2024 Solution View → 63

(9.3 ~g ) of pure aniline upon diazotisation followed by coupling with phenol gives an orange dye. The mass of orange dye produced (assume 100 % yield/conversion) is _______ g. (ne

JEE Main 2024 Solution View → 64

( X g ) of ethanamine was subjected to reaction with ( NaNO ₂ / HCl ) followed by hydrolysis to liberate ( N ₂ ) and ( HCl ). The ( HCl ) generated was completely neutralised by 0.

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Find out the major product formed from the following reaction. ( [ Me :- CH ₃ ] )

JEE Main 2024 Solution View → 66

Phthalimide is made to undergo following sequence of reactions. Total number of ( ) bonds present in product 'P' is/are ______

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From (6.55 ~g ) of aniline, the maximum amount of acetanilide that can be prepared will be ______ ( 10⁻¹ ~g ).

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( X g ) of ethylamine is subjected to reaction with ( NaNO ₂ / HCl ) followed by water; evolved dinitrogen gas which occupied (2.24 ~L ) volume at STP. ( X ) is ( ) ( 10⁻¹ ~g ).

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Number of compounds which give reaction with Hinsberg's reagent is _________.

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Given below are two statements: Statement (I) : The NH 2 group in Aniline is ortho and para directing and a powerful activating group. Statement (II) : Aniline does not undergo Fri

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Given below are two statements : Statement I: Aniline reacts with con. H 2 SO 4 followed by heating at 453 - 473 K gives p-aminobenzene sulphonic acid, which gives blood red colour

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A compound x with molar mass 108 g mol − 1 undergoes acetylation to give product with molar mass 192 g mol − 1 . The number of amino groups in the compound x is ________.

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The products A and B formed in the following reaction scheme are respectively

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Following is a confirmatory test for aromatic primary amines. Identify reagent (A) and (B)

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The final product A , formed in the following multistep reaction sequence is:

JEE Main 2024 Solution View → 76

Which of the following reaction is correct?

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The product A formed in the following reaction is:

JEE Main 2024 Solution View → 78

The total number of sp 2 hybridised carbon atoms in the major product P (a non-heterocyclic compound) of the following reaction is

JEE Advanced 2023 Solution View → 79

Consider the following sequence of reactions The product ‘ B ’ is

JEE Main 2023 Solution View → 80

In the above conversion the correct sequence of reagents to be added is

JEE Main 2023 Solution View → 81

Compound A from the following reaction sequence is :

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Compoun ' B ' is

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Isomeric amines with molecular formula C 8 H 11 N give the following tests Isomer P ⇒ Can be prepared by Gabriel phthalimide synthesis Isomer Q ⇒ Reacts with Hinsberg&r

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The product ( P ) formed from the following multistep reaction is:

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Match List I with List II : s reacted with reagents in List I to form products in List II products in List II. List I (Reagent) List II (Product) A. I. B. HBF 4 , Δ II. C. Cu,

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Number of isomeric aromatic amines with molecular formula C 8 H 11 N , which can be synthesized by Gabriel Phthalimide synthesis is _____.

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The major products A and B from the following reactions are :

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The major product formed in the following reaction is

JEE Main 2023 Solution View → 89

Compound P is neutral, Q gives effervescence with NaHCO 3 while R reacts with Hinsberg’s reagent to give solid soluble in NaOH . Compound P is

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In the following reaction, ‘ A ’ is

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An organic compound [ A ] C 4 H 11 N , shows optical activity and gives N 2 gas on treatment with HNO 2 . The compound [ A ] reacts with PhSO 2 Cl producing a compound which is sol

JEE Main 2023 Solution View → 92

How many of the transformation given below would result in aromatic amines?

JEE Main 2023 Solution View → 93

Benzyl isocyanide can be obtained by: (A) (B) (C) (D) Choose the correct answer from the options given below:

JEE Main 2023 Solution View → 94

Reaction of propanamide with Br 2 / KOH (aq) produces:

JEE Main 2023 Solution View → 95

The major product ' P ' for the following sequence of reactions is:

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Match List I with List II List I (Amines) List II pKb A. Aniline I. 3 . 25 B. Ethanamine II. 3 . 00 C. N-Ethylethanamine III. 9 . 38 D. N, N-Diethylethanamine IV. 3 . 29 Choose the

JEE Main 2023 Solution View → 97

The correct order in aqueous medium of basic strength in case of methyl substituted amines is:

JEE Main 2023 Solution View → 98

Identify the product formed ( A and E )

JEE Main 2023 Solution View → 99

Given below are two statements : Statement I : Pure Aniline and other arylamines are usually colourless. Statement II : Arylamines get coloured on storage due to atmospheric reduct

JEE Main 2023 Solution View → 100

Choose the correct colour of the product for the following reaction.

JEE Main 2023 Solution View → 101

Considering the following reaction sequence, the correct option(s) is(are)

JEE Advanced 2022 Solution View → 102

Match the compounds in LIST- I with the observations in LIST- II , and choose the correct option. LIST- I LIST- II I Aniline P Sodium fusion extract of the compound on boiling with

JEE Advanced 2022 Solution View → 103

The Hinsberg reagent is

JEE Main 2022 Solution View → 104

Which among the following is the strongest Bronsted base?

JEE Main 2022 Solution View → 105

Consider the above reaction, the compound ' A ' is

JEE Main 2022 Solution View → 106

Which among the following represent reagent ' A '?

JEE Main 2022 Solution View → 107

Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R Assertion A : Aniline on nitration yields ortho, meta & para nitro derivatives

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An organic compound ' A ' contains nitrogen and chlorine. It dissolves readily in water to give a solution that turns litmus red. Titration of compound ' A ' with s

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Match List-I with List-II List-I List-II A Benzenesulphonyl chloride I Test for primary amines B Hoffmann bromamide reaction II Anti Saytzeff C Carbylamine reaction III Hinsberg re

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Hydrolysis of which compound will give carbolic acid?

JEE Main 2022 Solution View → 111

The correct sequential order of the reagents for the given reaction is

JEE Main 2022 Solution View → 112

An organic compound ' A ' on reaction with NH 3 followed by heating gives compound B . Which on further strong heating gives compound C C 8 H 5 NO 2 . Compound C on sequent

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Consider the above reaction, the product A and product B respectively are

JEE Main 2022 Solution View → 114

With respect to the following reaction, consider the given statements: (A) o -Nitroaniline and p -nitroaniline are the predominant products. (B) p -Nitroaniline and m -nitroaniline

JEE Main 2022 Solution View → 115

Identify the major product formed in the following sequence of reactions :

JEE Main 2022 Solution View → 116

A primary aliphatic amine on reaction with nitrous acid in cold 273   K and there after raising temperature of reaction mixture to room temperature 298   K , gives a/an

JEE Main 2022 Solution View → 117

Given below are two statements : Statement - I : In Hofmann degradation reaction, the migration of only an alkyl group takes place from carbonyl carbon of the amide to the nitrogen

JEE Main 2022 Solution View → 118

Which statement is NOT correct for p-toluenesulphonyl chloride?

JEE Main 2022 Solution View → 119

Identify ' Z ' among the following

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Among the following structures, which will show the most stable enamine formation? (Where Me is - CH 3 )

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