JEE Main 20266 AprilMorning Shift
- Exam
- JEE Main
- Year
- 2026
- Date
- 6 April
- Shift
- Morning Shift
- Subject
- Chemistry
- Chapter
- Amines
JEE Main 2026 · 6 April · Morning Shift · Chemistry · Amines
Consider the following sequence of reactions. The percentage of...
Consider the following sequence of reactions.

The percentage of nitrogen in the yellow product (X) formed is _______%. (Nearest Integer) (Given Molar mass in g mol H:1, C:12, N:14)
The percentage of nitrogen in the yellow product (X) formed is _______%. (Nearest Integer) (Given Molar mass in g mol H:1, C:12, N:14)
Correct answer
0
Step-by-step solution
The given starting material is diazoaminobenzene ().
When diazoaminobenzene is treated with an acid catalyst (HCl) and excess aniline, and warmed to , it undergoes a rearrangement reaction (or dissociation followed by coupling) to form -aminoazobenzene.
The reaction sequence is as follows:
1. Diazoaminobenzene reacts with HCl to form benzenediazonium chloride and aniline.
2. The benzenediazonium ion then couples with the excess aniline at the para position to yield -aminoazobenzene.
3. Cooling and adding acetic acid helps in precipitating the free base, -aminoazobenzene, which is a yellow dye (often called Aniline Yellow).
The structure of the yellow product (X), -aminoazobenzene, is .
The molecular formula of -aminoazobenzene is .
Let's calculate its molar mass:
Molar mass
Molar mass
The mass of nitrogen in one mole of the compound is .
The percentage of nitrogen in the product is:
Rounding to the nearest integer, we get .
Answer:
When diazoaminobenzene is treated with an acid catalyst (HCl) and excess aniline, and warmed to , it undergoes a rearrangement reaction (or dissociation followed by coupling) to form -aminoazobenzene.
The reaction sequence is as follows:
1. Diazoaminobenzene reacts with HCl to form benzenediazonium chloride and aniline.
2. The benzenediazonium ion then couples with the excess aniline at the para position to yield -aminoazobenzene.
3. Cooling and adding acetic acid helps in precipitating the free base, -aminoazobenzene, which is a yellow dye (often called Aniline Yellow).
The structure of the yellow product (X), -aminoazobenzene, is .
The molecular formula of -aminoazobenzene is .
Let's calculate its molar mass:
Molar mass
Molar mass
The mass of nitrogen in one mole of the compound is .
The percentage of nitrogen in the product is:
Rounding to the nearest integer, we get .
Answer: