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JEE Main 20264 AprilMorning Shift
Exam
JEE Main
Year
2026
Date
4 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Chemical Kinetics

JEE Main 2026 · 4 April · Morning Shift · Chemistry · Chemical Kinetics

Consider the first order reaction R arrow P . The fraction of...

Consider the first order reaction R→PR \rightarrow P. The fraction of molecules decomposed in the given first order reaction can be expressed as

Options

  1. A1−ek1t1 - e^{k_1 t}
  2. B1+ek1t1 + e^{k_1 t}
  3. C1+e−k1t1 + e^{-k_1 t}
  4. D1−e−k1t1 - e^{-k_1 t}

Correct answer

D. 1−e−k1t1 - e^{-k_1 t}

Step-by-step solution

For a first order reaction, the concentration of reactant at time tt is given by

[R]t=[R]0e−k1t[R]_t = [R]_0 e^{-k_1 t}

The amount of reactant decomposed is

[R]0−[R]t=[R]0−[R]0e−k1t=[R]0(1−e−k1t)[R]_0 - [R]_t = [R]_0 - [R]_0 e^{-k_1 t} = [R]_0 (1 - e^{-k_1 t})

The fraction of molecules decomposed is

[R]0−[R]t[R]0=[R]0(1−e−k1t)[R]0=1−e−k1t\dfrac{[R]_0 - [R]_t}{[R]_0} = \dfrac{[R]_0 (1 - e^{-k_1 t})}{[R]_0} = 1 - e^{-k_1 t}

Answer: 1−e−k1t1 - e^{-k_1 t}
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