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JEE Main 202628 JanuaryMorning Shift
Exam
JEE Main
Year
2026
Date
28 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Chemical Kinetics

JEE Main 2026 · 28 January · Morning Shift · Chemistry · Chemical Kinetics

An organic compound undergoes first order decomposition. The time...

An organic compound undergoes first order decomposition. The time taken for decomposition to (18)th and(110)th \left(\frac{1}{8}\right)^{\text{th }} and \left(\frac{1}{10}\right)^{\text{th }} of its initial concentration are t1/8\mathrm{t}_{1/8} and t1/10\mathrm{t}_{1/10} respectively. What is the value of t1/8t1/10×10\frac{\mathrm{t}_{1/8}}{\mathrm{t}_{1/10}} \times 10 ? (log⁡2=0.3\log 2=0.3)

Options

  1. A3
  2. B9
  3. C0.9
  4. D30

Correct answer

B. 9

Step-by-step solution

For first-order decomposition with rate equation [A]=[A]0e−kt[A] = [A]_0 e^{-kt}, the time for concentration to reduce to fraction f is: t=1kln⁡1f=ln⁡(1/f)kt = \frac{1}{k}\ln\frac{1}{f} = \frac{\ln(1/f)}{k}
For reduction to 1/8: t1/8=ln⁡8k=3ln⁡2kt_{1/8} = \frac{\ln 8}{k} = \frac{3\ln 2}{k}
For reduction to 1/10: t1/10=ln⁡10kt_{1/10} = \frac{\ln 10}{k}
Therefore: t1/8t1/10=ln⁡8ln⁡10=3log⁡2log⁡10=3×0.31=0.9\frac{t_{1/8}}{t_{1/10}} = \frac{\ln 8}{\ln 10} = \frac{3\log 2}{\log 10} = \frac{3 \times 0.3}{1} = 0.9
Thus: t1/8t1/10×10=0.9×10=9\frac{t_{1/8}}{t_{1/10}} \times 10 = 0.9 \times 10 = 9
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