Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Main 202310 AprilEvening Shift
Exam
JEE Main
Year
2023
Date
10 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Chemical Kinetics

JEE Main 2023 · 10 April · Evening Shift · Chemistry · Chemical Kinetics

The number of incorrect statement/s from the following is...

The number of incorrect statement/s from the following is ______________

A. The successive half lives of zero order reactions decreases with time.

B. A substance appearing as reactant in the chemical equation may not affect the rate of reaction

C. Order and molecularity of a chemical reaction can be a fractional number

D. The rate constant units of zero and second order reaction are molL−1s−1molL - 1 {s}^{- 1} and mol−1Ls−1{mol}^{- 1}L{s}^{- 1} respectively

Correct answer

0

Step-by-step solution

A. C0⟶t=C02kC02⟶t=C04kC04⟶t=C08kC08{C}_{0}\overset{t = \dfrac{{C}_{0}}{2k}}{⟶}\dfrac{{C}_{0}}{2}\overset{t = \dfrac{{C}_{0}}{4k}}{⟶}\dfrac{{C}_{0}}{4}\overset{t = \dfrac{{C}_{0}}{8k}}{⟶}\dfrac{{C}_{0}}{8}

Successive half lives of zero order reactions decreases with time

Note: successive half lives of first order reactions remains same

B. For zero order reactions, the rate of reaction is independent on the concentration of reactants.

C. In some reaction molecularity (theoretical value) may be equal to the order of a reaction (experimental value). The order of a reaction may be fractional, zero, positive or negative. Molecularity can never be fractional.

(D) Unit of k=Unitsofrate[ unitsofconcentration ] order k = \dfrac{Unitsofrate}{{\left[\text{ unitsofconcentration }\right]}^{\text{ order }}}</p><p>Zeroorder</p><p>Zero order= {mollit}^{- 1}\sec^{- 1}</p><p>Secondorder</p><p>Second order= {mol}^{- 1}{lit}^{- 1}

Practice Chemical Kinetics on Quantrex Academy →

More from Chemical Kinetics

For a reversible reaction R leftharpoons P , at constant temperature, both the forward… JEE Advanced 2026For a first-order reaction R P at a given temperature, k is the rate constant. For this… JEE Advanced 2026Given below are two statements: R=8.314 J K ^ -1 mol ^ -1 and 1 cal =4.2 J Statement I… JEE Main 2026Decomposition of a hydrocarbon follows the equation k = (5.5 × 10^ 11 \,s^ -1 )\,e^… JEE Main 2026For a reaction A arrow P at T K , the half life (t_ 1/2 ) is plotted as a function of… JEE Main 2026First order gas phase reaction A arrow B + C p_i = initial pressure of gas A, p_t = total… JEE Main 2026If the half life of a first order reaction is 6.93 minutes then the time required for… JEE Main 2026Consider the given graph showing variation of reactant concentration with time. Three… JEE Main 2026 Full Chemical Kinetics list All JEE Main PYQs