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JEE Main 202310 AprilMorning Shift
Exam
JEE Main
Year
2023
Date
10 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Chemical Kinetics

JEE Main 2023 · 10 April · Morning Shift · Chemistry · Chemical Kinetics

A molecule undergoes two independent first order reactions whose...

A molecule undergoes two independent first order reactions whose respective half lives are 12min12min and 3min3min. If both the reactions are occurring then the time taken for the 5050 % consumption of the reactant is ______ minmin. (Nearest integer)A molecule undergoes two independent first order reactions whose respective half lives are 12min and 3min . If both the

Correct answer

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Step-by-step solution

For parallel reaction

A molecule undergoes two independent first order reactions whose respective half lives are 12min and 3min . If both the

When adding the rate constants of the two reactions, we need to use the formula for combining rate constants of two reactions in parallel, which is:

k=k1+k2k = {k}_{1} + {k}_{2}

where k1{k}_{1} and k2{k}_{2} are the rate constants of the individual reactions.

In this case, the half-lives of the two reactions are 1212 min and 33 min, respectively. The rate constants of the two reactions can be calculated using the formula for half-life of a first-order reaction:

1t1/2=112+13=512\dfrac{1}{{t}_{1/2}} = \dfrac{1}{12} + \dfrac{1}{3} = \dfrac{5}{12}

Net t1/2=125=2.4min≈2min{t}_{1/2} = \dfrac{12}{5} = 2 . 4min \approx 2min

Hence time taken for 5050 % consumption of reactant will be close to 2min2min.

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